1-Ethoxy-4-(methylselanyl)benzene

Base Information

• Chemical Name: 1-Ethoxy-4-(methylselanyl)benzene
• CAS No.: 86297-06-5
• Molecular Formula: C9H12OSe
• Molecular Weight: 215.154
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID60574696
• Wikidata: Q82463838
• Mol file: 86297-06-5.mol

Synonyms:86297-06-5;1-Ethoxy-4-(methylselanyl)benzene;DTXSID60574696

Chemical Property of 1-Ethoxy-4-(methylselanyl)benzene

Chemical Property:

• PSA: 9.23000
• LogP: 1.46290
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 216.00534
• Heavy Atom Count: 11
• Complexity: 97.7

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC1=CC=C(C=C1)[Se]C

Technology Process of 1-Ethoxy-4-(methylselanyl)benzene

There total 1 articles about 1-Ethoxy-4-(methylselanyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

1-ethoxy-4-iodobenzene (699-08-1) + Seleno-L-methionine (3211-76-5) → 1-Ethoxy-4-methylselanyl-benzene (86297-06-5)

Guidance literature:

With potassium tert-butylate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; palladium dichloride; In 5,5-dimethyl-1,3-cyclohexadiene; at 130 ℃; for 12h;

DOI:10.1039/c9sc05532k

Reference yield:

1-Ethoxy-4-methylselanyl-benzene (86297-06-5) → bis-(p-ethoxyphenyl)-diselenide (67462-01-5)

Guidance literature:

With iodine; sodium thioethylate; Yield given. Multistep reaction; 1.) HMPT, reflux, 8 h; 2.) room temp.;

DOI:10.1016/S0040-4039(00)81412-4

upstream raw materials:

1-ethoxy-4-iodobenzene

Seleno-L-methionine

Downstream raw materials:

bis-(p-ethoxyphenyl)-diselenide

Refernces