Borate(1-), tetrakis[3,5-bis(trifluoroMethyl)phenyl]-, sodiuM, hydrate (9CI)

Base Information

• Chemical Name: Borate(1-), tetrakis[3,5-bis(trifluoroMethyl)phenyl]-, sodiuM, hydrate (9CI)
• CAS No.: 455330-37-7
• Molecular Formula: C₃₂H₁₂BF₂₄*2H₂O*Na
• Molecular Weight: 922.24
• Mol file: 455330-37-7.mol

Synonyms:Borate(1-), tetrakis[3,5-bis(trifluoroMethyl)phenyl]-, sodiuM, hydrate (9CI);Sodium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate xhydrate

Chemical Property of Borate(1-), tetrakis[3,5-bis(trifluoroMethyl)phenyl]-, sodiuM, hydrate (9CI)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Sodiumtetrakis(3,5-bis(trifluoromethyl)phenyl)boratexhydrate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Borate(1-), tetrakis[3,5-bis(trifluoroMethyl)phenyl]-, sodiuM, hydrate (9CI)

There total 2 articles about Borate(1-), tetrakis[3,5-bis(trifluoroMethyl)phenyl]-, sodiuM, hydrate (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium tetrafluoroborate (13755-29-8) + 3,6-bis(trifluoromethyl)bromobenzene (328-70-1) → sodium tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate dihydrate (455330-37-7)

Guidance literature:

With Mg; dibromoethane; In diethyl ether; NaBF4, Mg and dibromoethane in Et2O were heated over 30 min, BrC6H3(CF3)2 was added and heated over 30 min; Na2CO3 in water was added, stirred for 30 min and filtered, organic layer was dried over Na2SO4, solvent was removed, residue was dissolve in benzene and water was distilled off; elem. anal.;

DOI:10.1021/ic0100121

Reference yield:

sodium tetrafluoroborate (13755-29-8) + water (7732-18-5) + 3,5-bis(trifluoromethyl)phenylmagnesium bromide (112981-69-8) → sodium tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate dihydrate (455330-37-7)

Guidance literature:

In tetrahydrofuran;

DOI:10.1021/ic061162k

Reference yield: 96.0%

1-Phenylprop-1-yne (673-32-5) + sodium tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate dihydrate (455330-37-7) + [Cp*RhCl(C6H4Me-m)(PMe3)] (1607815-55-3) → [Cp*Rh{C6H3-2-(C(Me)=CHPh)-4-Me}(PMe3)][(B3,5-(CF3)2C6H3)4]

Guidance literature:

In 1,2-dichloro-ethane; at 25 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1021/om5003232

upstream raw materials:

sodium tetrafluoroborate

water

3,5-bis(trifluoromethyl)phenylmagnesium bromide

3,6-bis(trifluoromethyl)bromobenzene

Downstream raw materials:

fac-Re(2,2'-bipyridine)(CO)3(P(OC₆H₁₃)3)[tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

[(η5-C5H5)Ru(η2-diphenylacetylene)(Ph2PCH2PPh2)][B(3,5-(CF3)2C6H3)4]

Refernces

• 1、 Reger,Wright,Little,Lamba,Smith. "Control of the stereochemical impact of the lone pair in lead(II) tris(pyrazolyl)methane complexes. Improved preparation of Na{B[3,5-(CF3)2C6H3]4}". . p. 3810 - 3814. Retrieved 2001.