Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Base Information

• Chemical Name: Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
• CAS No.: 79060-88-1
• Molecular Formula: C32H12BF24Na
• Molecular Weight: 886.21
• Hs Code.: 29319090
• Mol file: 79060-88-1.mol

Synonyms:Borate(1-),tetrakis[3,5-bis(trifluoromethyl)phenyl]-, sodium (9CI);Sodiumtetrakis(3,5-bis(trifluoromethyl)phenyl)borate(1-);Sodiumtetrakis[3,5-bis(trifluoromethyl)phenyl]borate;Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate sodium salt;

Chemical Property of Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Chemical Property:

• Appearance/Colour: Light beige powder
• Melting Point: 310℃
• PSA: 0.00000
• LogP: 11.21440
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility.: DMSO (Slightly)
• Water Solubility.: soluble

Purity/Quality:

98%,99%, ^*data from raw suppliers

Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,Xi
• Hazard Codes: Xn,Xi
• Statements: 36/37/38-20/21/22
• Safety Statements: 36/37/39-26-22

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, also known as the BARF anion, is a compound used in catalytic cycles due to its inability to coordinate to metal centres. Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate was used in the preparation of poly(n-butyl acrylate)- based ion-selective membranes.

Technology Process of Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

There total 8 articles about Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

sodium tetrafluoroborate (13755-29-8) + 3,6-bis(trifluoromethyl)bromobenzene (328-70-1) → sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1)

Guidance literature:

With magnesium; In diethyl ether; ethylene dibromide; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/acs.inorgchem.1c00042

Reference yield: 78.0%

3,6-bis(trifluoromethyl)bromobenzene (328-70-1) → sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1)

Guidance literature:

With sodium tetrafluoroborate; magnesium; ethylene dibromide; In diethyl ether; Reflux;

DOI:10.1002/chem.202101961

Reference yield: 68.0%

3,6-bis(trifluoromethyl)bromobenzene (328-70-1) + boron trifluoride diethyl etherate (109-63-7) + sodium carbonate (497-19-8) → sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1)

Guidance literature:

3,6-bis(trifluoromethyl)bromobenzene; With iodine; magnesium; In diethyl ether; at 20 ℃; for 4h;

boron trifluoride diethyl etherate; In diethyl ether; at 40 ℃; for 12h;

sodium carbonate; In diethyl ether; water;

DOI:10.1039/c9dt00235a

upstream raw materials:

3,6-bis(trifluoromethyl)bromobenzene

sodium carbonate

sodium tetrafluoroborate

sodium tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate dihydrate

Downstream raw materials:

CH₂CCH₃CH₂OP(N(CH₃)2)3⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=CH₂CCH₃CH₂OP(N(CH₃)2)3B(C₆H₃(CF₃)2)4

Refernces

• 1、 Brookhart,Grant,Volpe Jr.. "[(3,5-(CF3)2C6H3) 4B]-[H(OEt2)2]+: A convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes". . p. 3920 - 3922. Retrieved 1992.
• 2、 Korb, Marcus,Hosseini Ghazvini, Seyed Mohammad Bagher,Moggach, Stephen A.,Meunier, Jean-Fran?ois,Bousseksou, Azzedine,Low, Paul J.. "Rip It off: Nitro to Nitroso Reduction by Iron Half-Sandwich Complexes". supporting information. p. 4986 - 4995. Retrieved 2021/04/06.
• 3、 Kaasik, Mikk,Metsala, Andrus,Kaabel, Sandra,Kriis, Kadri,J?rving, Ivar,Kanger, Tonis. "Halo-1,2,3-triazolium salts as halogen bond donors for the activation of imines in dihydropyridinone synthesis". . p. 4295 - 4303. Retrieved 2019/03/29.