N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine

Base Information

• Chemical Name: N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine
• CAS No.: 3261-60-7
• Molecular Formula: C16H17NO2
• Molecular Weight: 255.316
• Hs Code.: 2922299090
• Mol file: 3261-60-7.mol

Synonyms:N-(4-Methoxybenzyl)-4-methoxybenzenemethanimine;N-(4-Methoxybenzylidene)-4-methoxybenzenemethanamine;N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine;N-(p-Methoxybenzylidene)-p-methoxybenzylamine

Chemical Property of N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine

Chemical Property:

• Melting Point: 37-38 °C
• Boiling Point: 125 °C(Press: 14 Torr)
• PKA: 5.28±0.50(Predicted)
• PSA: 30.82000
• Density: 1.02±0.1 g/cm3(Predicted)
• LogP: 3.32290

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine

There total 48 articles about N-(4-Methoxybenzylidene)-N-(4-methoxybenzyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-methoxy-benzylamine (2393-23-9) → N-(4-methoxybenzylidene)-4-methoxybenzylamine (3261-60-7)

Guidance literature:

With oxygen; methylene blue; potassium carbonate; In acetonitrile; at 20 ℃; for 10h; Irradiation; Green chemistry;

DOI:10.1055/s-0034-1379923

Reference yield: 90.0%

4-methoxy-benzylamine (2393-23-9) → N-(4-methoxybenzylidene)-4-methoxybenzylamine (3261-60-7) + 4-methoxybenzonitrile (874-90-8)

Guidance literature:

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; C₆₃H₅₁N₂O₃P₂Ru⁽¹⁺⁾*ClO₄^(1-); oxygen; In toluene; at 90 ℃; for 20h; under 760.051 Torr;

DOI:10.1039/c6cc10200j

Reference yield: 80.0%

4-methoxy-benzylamine (2393-23-9) → N-(4-methoxybenzylidene)-4-methoxybenzylamine (3261-60-7) + 4-methoxy-benzaldehyde (123-11-5) + 4-methoxybenzonitrile (874-90-8)

Guidance literature:

With sodium hypochlorite; In ethanol; for 0.25h; Ambient temperature;

DOI:10.1080/00397919708007077

upstream raw materials:

4-methoxy-benzaldehyde

4-methoxy-benzylamine

1-(azidomethyl)-4-methoxybenzene

4-Methoxybenzyl alcohol

Downstream raw materials:

(R)-2-(bis(4-methoxybenzyl)amino)-N-(tert-butyl)-2-phenylacetamide

(E)-2-(2-(4-methoxyphenyl)vinyl)quinoline

1-(4-methoxybenzyl)-2-(4-methoxyphenyl)-1H-benzimidazole

Refernces

• 1、 Liu, Bo,Pan, Jing,Shi, Weidong,Song, Shuyan,Wang, Huilin,Wang, Xiao,Xu, Jing,Zhang, Hongjie,Zhang, Lingling,Zhao, Meng. "Ball-Milling Induced Debonding of Surface Atoms from Metal Bulk for Construing High-Performance Dual-Site Single-Atom Catalysts". supporting information. p. 23154 - 23158. Retrieved 2021/09/15.
• 2、 -. "Method for preparing N -benzyl allylamine by high-efficiency photo-catalytic oxidation of xylylenediamine". Paragraph 0020-0049. . Retrieved 2021/11/03.