Deacetyl asperulosidic acid methyl ester

Base Information

• Chemical Name: Deacetyl asperulosidic acid methyl ester
• CAS No.: 52613-28-2
• Molecular Formula: C17H24O11
• Molecular Weight: 404.37
• Hs Code.: 29389090
• Mol file: 52613-28-2.mol

Synonyms:Deacetyl asperulosidic acid methyl ester;6-alpha-Hydroxygeniposide

Chemical Property of Deacetyl asperulosidic acid methyl ester

Chemical Property:

• Boiling Point: 696.3±55.0 °C(Predicted)
• PKA: 12.80±0.70(Predicted)
• PSA: 175.37000
• Density: 1.61±0.1 g/cm3(Predicted)
• LogP: -3.25830

Purity/Quality:

98%Min ^*data from raw suppliers

6α-Hydroxygeniposide 95+% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Deacetyl asperulosidic acid methyl ester

There total 5 articles about Deacetyl asperulosidic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

asperuloside (14259-45-1) → 6α-hydroxygeniposide (27530-67-2,52613-28-2)

Guidance literature:

With sodium methylate; In methanol; for 2h; Ambient temperature;

DOI:10.1016/0031-9422(80)85068-0

Reference yield:

3-(4-Hydroxy-phenyl)-propionic acid (2aS,4aS,5S,7bS)-1-oxo-5-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-2a,4a,5,7b-tetrahydro-1H-2,6-dioxa-cyclopenta[cd]inden-4-ylmethyl ester → 6α-hydroxygeniposide (27530-67-2,52613-28-2)

Guidance literature:

With sodium methylate; In methanol;

DOI:10.1016/0031-9422(80)85068-0

Reference yield:

→ Scandosid-methylester (27530-67-2,52613-28-2)

Guidance literature:

Scandosid, Diazomethan in Ae.;

upstream raw materials:

asperuloside

Refernces