4-BAPC

Base Information

• Chemical Name: 4-BAPC
• CAS No.: 1370555-65-9
• Molecular Formula: C18H14BNO2
• Molecular Weight: 287.12
• Mol file: 1370555-65-9.mol

Synonyms:4-BAPC;(9-phenyl-9H-carbazol-4-yl)boronic acid;B-(9-phenyl-9H-carbazol-4-yl)-Boronic acid

Chemical Property of 4-BAPC

Chemical Property:

• Boiling Point: 466.0±51.0 °C(Predicted)
• PKA: 8.91±0.30(Predicted)
• PSA: 45.39000
• Density: 1.20±0.1 g/cm3(Predicted)
• LogP: 2.46350

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-BAPC

There total 14 articles about 4-BAPC which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

Triisopropyl borate (5419-55-6) + 4-bromo-9-diphenyl-9H-carbazole (1097884-37-1) + water (7732-18-5) → (9-phenyl-9H-carbazol-4-yl)boronic acid (1370555-65-9)

Guidance literature:

4-bromo-9-diphenyl-9H-carbazole; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.5h;

Triisopropyl borate; In diethyl ether; hexane; at -78 - 20 ℃;

water; With hydrogenchloride; In diethyl ether; hexane;

Reference yield: 72.0%

Trimethyl borate (121-43-7,63156-11-6) + 4-bromo-9-diphenyl-9H-carbazole (1097884-37-1) → (9-phenyl-9H-carbazol-4-yl)boronic acid (1370555-65-9)

Guidance literature:

4-bromo-9-diphenyl-9H-carbazole; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

Trimethyl borate; In tetrahydrofuran; at 20 ℃;

Reference yield: 71.0%

Triisopropyl borate (5419-55-6) + 4-bromo-9-diphenyl-9H-carbazole (1097884-37-1) → (9-phenyl-9H-carbazol-4-yl)boronic acid (1370555-65-9)

Guidance literature:

4-bromo-9-diphenyl-9H-carbazole; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.5h;

Triisopropyl borate; In diethyl ether; hexane; at -78 - 20 ℃;

With hydrogenchloride; In diethyl ether; hexane; water; at 20 ℃;

upstream raw materials:

4-bromo-9-diphenyl-9H-carbazole

Triisopropyl borate

phenylboronic acid

1-bromo-2-iodo-3-nitro-benzene

Refernces

• 1、 -. "Deuterated organic compounds for organic light-emitting diode and organic light-emitting diode including the same". . . Retrieved 2020/04/30.
• 2、 -. "Organic electro-luminescent compound and organic electro-luminescent device using same". . . Retrieved 2018/03/26.