4-broMo-9-phenyl-9H-carbazole

Base Information

• Chemical Name: 4-broMo-9-phenyl-9H-carbazole
• CAS No.: 1097884-37-1
• Molecular Formula: C18H12BrN
• Molecular Weight: 322.204
• Mol file: 1097884-37-1.mol

Synonyms:4-broMo-9-phenyl-9H-carbazole

Chemical Property of 4-broMo-9-phenyl-9H-carbazole

Chemical Property:

• Boiling Point: 461.7±27.0 °C(Predicted)
• PSA: 4.93000
• Density: 1.39±0.1 g/cm3(Predicted)
• LogP: 5.54620

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Bromo-9-phenyl-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-broMo-9-phenyl-9H-carbazole

There total 11 articles about 4-broMo-9-phenyl-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

4-bromo-9H-carbazole (3652-89-9) + iodobenzene (591-50-4) → 4-bromo-9-diphenyl-9H-carbazole (1097884-37-1)

Guidance literature:

With copper(l) iodide; potassium carbonate; 1-(2-pyridyl)-3-(2-pyridyl)-1,3-propanedione; In N,N-dimethyl-formamide; at 110 ℃; Inert atmosphere;

Reference yield: 95.0%

4-bromo-9H-carbazole (3652-89-9) + phenylhydrazine (100-63-0) → 4-bromo-9-diphenyl-9H-carbazole (1097884-37-1)

Guidance literature:

With copper(l) iodide; caesium carbonate; In acetonitrile; at 0 ℃; for 4h; Schlenk technique;

Reference yield: 86.0%

→ 4-bromo-9-diphenyl-9H-carbazole (1097884-37-1)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; for 1h;

In N,N-dimethyl-formamide;

upstream raw materials:

(2-bromophenyl)boronic acid

2-nitrophenyl bromide

2-bromo-2′-nitro-1,1′-biphenyl

bromobenzene

Downstream raw materials:

(9-phenyl-9H-carbazol-4-yl)boronic acid

Refernces

• 1、 Kang, Seokwoo,Jung, Hyocheol,Lee, Hayoon,Lee, Suji,Jung, Mina,Lee, Jaehyun,Chul Kim, Young,Park, Jongwook. "Blue light emission of new anthracene derivatives produced using optimized side group link positions". . p. 369 - 378. Retrieved 2018.
• 2、 -. "Organic electroluminescent material and device thereof". Paragraph 0110; 0111-0113. . Retrieved 2020/05/14.
• 3、 -. "Deuterated organic compounds for organic light-emitting diode and organic light-emitting diode including the same". Paragraph 0476; 0482-0486. . Retrieved 2020/12/15.