RutheniuM(III) chloride hydrate

Base Information

• Chemical Name: RutheniuM(III) chloride hydrate
• CAS No.: 20759-14-2
• Molecular Formula: Cl3H2ORu
• Molecular Weight: 225.444
• Hs Code.: 2915900090
• Mol file: 20759-14-2.mol

Synonyms:ruthenium trichloride monohydrate;IN3062;

Chemical Property of RutheniuM(III) chloride hydrate

Chemical Property:

• PSA: 9.23000
• LogP: -9.05230
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

Ruthenium(III) chloride hydrate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of RutheniuM(III) chloride hydrate

There total 2 articles about RutheniuM(III) chloride hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

water (7732-18-5) + ruthenium(III)chloride (10049-08-8,63767-78-2) → ruthenium(III) chloride hydrate (20759-14-2,14898-67-0)

Guidance literature:

With HCl; In hydrogenchloride; Electrolysis; soln. of RuCl3 in 2n HCl is electrolysed as catholyte; subsequent concn. of the red soln. in HCl-stream under exclusion of air first at the b.p., later at 80-100°C to dryness;; drying over concd. H2SO4 in vacuum leads to a product free from Ru(IV);;

Reference yield:

ruthenium(IV) hydroxide (12181-34-9) → ruthenium(III) chloride hydrate (20759-14-2,14898-67-0)

Guidance literature:

With hydrogenchloride; In hydrogenchloride; dissolving Ru(OH)4 in HCl (100°C), addn. of H2C2O4; according to Shorikov, Yu. S., et al., Zh. Neorg. Khim., 1984, 29(12), 2999; (Russ. J. Inorg. Chem., 1984(12)); evapn., drying (vac. over alkali, room temp.); elem. anal.;

Reference yield: 99.0%

ruthenium(III) chloride hydrate (20759-14-2,14898-67-0) + N,N'-didodecyl-4,4'-{[2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl)}dibenzamide (841234-02-4) → trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III) (841234-12-6)

Guidance literature:

In ethanol; suspn. of RuCl3*H2O and ligand in ethanol was refluxed for 6 h under Ar; cooled; filtered; washed (H2O, EtOH); dried;

DOI:10.1002/hlca.200490262

upstream raw materials:

water

ruthenium(III)chloride

ruthenium(IV) hydroxide

Downstream raw materials:

trans-3-oxospiro[isobenzofuran-1(3H),1'-cyclohexane]-4'-carboxylic acid

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

cis-dichlorobis(2,2′-bipyridine)ruthenium(II)

ruthenium