Phenol, o-(p-bromophenylformimidoyl)-

Base Information

• Chemical Name: Phenol, o-(p-bromophenylformimidoyl)-
• CAS No.: 886-34-0
• Molecular Formula: C₁₃H₁₀BrNO
• Molecular Weight: 276.132
• Hs Code.: 2925290090
• European Community (EC) Number: 654-940-7
• NSC Number: 526319
• UNII: 8M9U8EX2WE
• DSSTox Substance ID: DTXSID00419774,DTXSID601282790
• Nikkaji Number: J48.507A
• Mol file: 886-34-0.mol

Synonyms:886-34-0;Salicylidene p-bromoaniline;Phenol, o-(p-bromophenylformimidoyl)-;Salicylaldehyde 4-bromanil;2-(((4-Bromophenyl)imino)methyl)phenol;N-SALICYLIDENE P-BROMOANILINE;Salicylidene-p-bromoaniline;2-{(E)-[(4-bromophenyl)imino]methyl}phenol;o-CRESOL, alpha-(p-BROMOPHENYLIMINO)-;alpha-(4-Bromophenylimino)-o-cresol;2-[(4-bromophenyl)iminomethyl]phenol;53565-63-2;C13H10BrNO;NSC 526319;o-(N-(p-Bromophenyl)formimidoyl)phenol;Phenol, o-(N-(p-bromophenyl)formimidoyl)-;Phenol, 2-(((4-bromophenyl)imino)methyl)-;2,4-Cyclohexadien-1-one, 6-[[(4-bromophenyl)amino]methylene]-;NSC-526319;.alpha.-(4-bromophenylimino)-o-cresol;o-Cresol, .alpha.-(p-bromophenylimino)-;.alpha.-(4-Bromophenylimino)-ortho-cresol;Phenol, 2-[[(4-bromophenyl)imino]methyl]-;2-[(E)-[(4-bromophenyl)imino]methyl]phenol;2-[[(4-Bromophenyl)imino]methyl]phenol;2-{[(4-bromophenyl)imino]methyl}phenol;Salicylidene-(p-bromoanil);NSC526319;2-[N-(4-bromophenyl)carboximidoyl]phenol;Enamine_001248;WLN: QR B1UNR DE;8M9U8EX2WE;N-salicylidene-4-bromoaniline;4-Bromo-N-salicylideneaniline;SCHEMBL5784154;N-(p-Bromophenyl)salicylaldimine;DTXSID00419774;DTXSID601282790;HMS1397I16;MFCD00020088;STK926113;AKOS000591435;AKOS004906530;4-Bromo-N-(2-hydroxybenzylidene)aniline;82306-72-7;BS-10363;LS-55334;(E)-2-((4-bromophenylimino)methyl)phenol;Phenol, o-[N-(p-bromophenyl)formimidoyl];2-phenylaminomethylene-malonicaciddiethylester;CS-0326085;FT-0676065;2-((E)-[(4-Bromophenyl)imino]methyl)phenol #;phenol, 2-[(E)-[(4-bromophenyl)imino]methyl]-;Z56791249;(E)-2-(((4-Bromophenyl)imino)methyl)phenol, AldrichCPR

Chemical Property of Phenol, o-(p-bromophenylformimidoyl)-

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 401.086°C at 760 mmHg
• Flash Point: 196.37°C
• PSA: 32.59000
• Density: 1.385g/cm³
• LogP: 3.90530
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 274.99458
• Heavy Atom Count: 16
• Complexity: 236

Purity/Quality:

99% ^*data from raw suppliers

Salicylidene p-bromoaniline ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C=NC2=CC=C(C=C2)Br)O

Technology Process of Phenol, o-(p-bromophenylformimidoyl)-

There total 8 articles about Phenol, o-(p-bromophenylformimidoyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

salicylaldehyde (90-02-8) + 4-bromo-aniline (106-40-1) → N-salicylidene 4-bromoaniline (886-34-0,82306-72-7)

Guidance literature:

In ethyl 2-hydroxypropionate; water; at 20 ℃; for 0.05h;

DOI:10.1039/b817379f

Reference yield: 96.0%

→ N-salicylidene 4-bromoaniline (886-34-0,82306-72-7)

Guidance literature:

Reference yield: 90.0%

salicylic alcohol (90-01-7) + 4-bromo-aniline (106-40-1) → N-salicylidene 4-bromoaniline (886-34-0,82306-72-7)

Guidance literature:

salicylic alcohol; With tert.-butylhydroperoxide; Cu₂(bbda)_0.5(Hbbda)_1.5(OAc)_1.5.8H₂O; In neat (no solvent); at 40 ℃;

4-bromo-aniline; In neat (no solvent); at 20 ℃;

DOI:10.1002/aoc.5965

upstream raw materials:

salicylaldehyde

4-bromo-aniline

methanol

WOCl₃(C₁₃H₉NOBr)

Downstream raw materials:

N-(4-bromophenyl)-N-(2,3-dihydrobenzo[b]furan-3-yl)amine

MoO₂((C₆H₄)(O)(CHN(C₆H₄)(Br)))2

(O)C₆H₄OBOC₆H₄CHNC₆H₄Br

Refernces

• 1、 Xiao, Yan,Cao, Chenzhong. "Influence of substituents on the structure of Schiff bases Cu(II) complexes". . . Retrieved 2020/02/29.
• 2、 Jaiswal, Nitesh,Kushwaha, Ajeet Kumar,Singh, Avadhesh Pratap,Dubey, Raj Kumar. "Synthesis, spectroscopic characterization and computational studies of Schiff base complexes of tin(IV) chloride". . p. 28 - 36. Retrieved 2019/06/24.