(4-Nitrophenyl)acetic acid 4-nitrophenyl ester

Base Information

• Chemical Name: (4-Nitrophenyl)acetic acid 4-nitrophenyl ester
• CAS No.: 35665-94-2
• Molecular Formula: C14H10N2O6
• Molecular Weight: 302.243
• Mol file: 35665-94-2.mol

Synonyms:(4-Nitrophenyl)acetic acid 4-nitrophenyl ester;4-Nitrobenzeneacetic acid 4-nitrophenyl ester

Chemical Property of (4-Nitrophenyl)acetic acid 4-nitrophenyl ester

Chemical Property:

• PSA: 117.94000
• LogP: 3.69750

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (4-Nitrophenyl)acetic acid 4-nitrophenyl ester

There total 2 articles about (4-Nitrophenyl)acetic acid 4-nitrophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 4-nitrophenylacetyl chloride (50434-36-1) → p-nitrophenyl p-nitrophenylacetate (35665-94-2)

Guidance literature:

In xylene; Heating;

DOI:10.1021/jo00319a028

Reference yield:

4-nitrophenol sodium salt (824-78-2) + 4-nitrophenylacetyl chloride (50434-36-1) → p-nitrophenyl p-nitrophenylacetate (35665-94-2)

Guidance literature:

In benzene;

Reference yield:

p-nitrophenyl p-nitrophenylacetate (35665-94-2) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 4-nitrobenzeneacetic acid (104-03-0)

Guidance literature:

With barium dihydroxide; In water; dimethyl sulfoxide; at 30 ℃; Rate constant; Mechanism;

DOI:10.1021/jo00319a028

upstream raw materials:

4-nitro-phenol

4-nitrophenylacetyl chloride

4-nitrophenol sodium salt

Downstream raw materials:

4-nitro-phenol

4-nitrobenzeneacetic acid

4-nitrophenylketene

p-nitrophenolate

Refernces

• 1、 Broxton Trevor, J.,Duddy, Neil W.. "Hydrolysis of Esters and Amides in Strongly Basic Solution. Evidence for the Intermediacy of Carbanions". . p. 1186 - 1191. Retrieved 2007/10/02.