Mn(III) Meso-Tetra(2,4,6-triMethylphenyl)porphine chloride

Base Information

• Chemical Name: Mn(III) Meso-Tetra(2,4,6-triMethylphenyl)porphine chloride
• CAS No.: 85939-49-7
• Molecular Formula: C₅₆H₅₂ClMnN₄
• Molecular Weight: 871.447
• Mol file: 85939-49-7.mol

Synonyms:Mn(III) Meso-Tetra(2,4,6-triMethylphenyl)porphine chloride

Chemical Property of Mn(III) Meso-Tetra(2,4,6-triMethylphenyl)porphine chloride

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Mn(III) Meso-Tetra(2,4,6-triMethylphenyl)porphine chloride

There total 8 articles about Mn(III) Meso-Tetra(2,4,6-triMethylphenyl)porphine chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

5,10,15,20-tetramesitylporphyrin + manganese (II) acetate tetrahydrate (6156-78-1) → (5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride (85939-49-7)

Guidance literature:

In N,N-dimethyl-formamide; according to Alder et al., J. Inorg. Nucl. Chem. 1970, 2443; refluxing for 4 h; recrystn. (CH2Cl2/hexane=1:1);

Reference yield: 82.0%

5,10,15,20-tetramesitylporphyrin + manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3) → (5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride (85939-49-7)

Guidance literature:

5,10,15,20-tetramesitylporphyrin; manganese(II) acetate; In N,N-dimethyl-formamide; for 6h; Inert atmosphere; Reflux;

With hydrogenchloride; In dichloromethane; water; at 20 ℃; for 0.166667h; Inert atmosphere;

DOI:10.1002/chem.201202640

Reference yield: 65.0%

→ (5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride (85939-49-7)

Guidance literature:

upstream raw materials:

manganese (II) acetate tetrahydrate

trans-dichloro(5,10,15,20-tetramesitylporphyrinato)manganese(IV)

5,10,15,20-tetramesitylporphyrin

manganese(II) acetate

Downstream raw materials:

Mn(5,10,15,20-tetrakis(2,4,6-trimethylphenyl)porphyrinate)OCl

5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo

hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III)

trans-dichloro(5,10,15,20-tetramesitylporphyrinato)manganese(IV)

Refernces

• 1、 Ikezaki, Akira,Nakamura, Mikio. "Effects of porphyrin deformation on the 13 C and 1H NMR chemical shifts in high-spin five-and six-coordinate manganese(III) porphyrin complexes". . p. 318 - 330. Retrieved 2016/07/07.
• 2、 -. "PROCESSES FOR THE PREPARATION OF ARTEMISININ AN ITS PRECURSORS". Page/Page column 37-38. . Retrieved 2009/09/04.