hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III)

Base Information

• Chemical Name: hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III)
• CAS No.: 105694-20-0
• Molecular Formula: C₅₆H₅₃MnN₄O
• Molecular Weight: 853.001
• Mol file: 105694-20-0.mol

Synonyms:hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III)

Chemical Property of hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III)

There total 8 articles about hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride (85939-49-7) → hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III) (105694-20-0)

Guidance literature:

With NaOH; In benzene; refluxing for several hours; cooling and washing of the organic phase with water, evapn. of the solvent. vac.-drying of the solid;

DOI:10.1021/ja00234a009

Reference yield:

1,1'-dimethylferrocene (1291-47-0) + 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo (115775-87-6) → hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III) (105694-20-0)

Guidance literature:

In acetonitrile; byproducts: 1,1'-dimethylferrocenium; CH3CN, 298 K; not isolated, detected by spectrophotometrically; Kinetics;

DOI:10.1021/ja9045235

Reference yield:

bromoferrocene (1273-73-0) + 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo (115775-87-6) → hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III) (105694-20-0)

Guidance literature:

In acetonitrile; byproducts: bromoferrocenium; CH3CN, 298 K; not isolated, detected by spectrophotometrically; Kinetics;

DOI:10.1021/ja9045235

upstream raw materials:

(5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride

5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo

9,10-Dimethylacridane

10-methyl-9-phenyl-9,10-dihydroacridine

Downstream raw materials:

5,10,15,20-tetrakis-(2',4',6'-trimethylphenyl)manganeseporphyrinate

Mn(IV)(O)(OH)(tetramesitylporphyrin)

Refernces

• 1、 Groves, John T.,Stern, Michael K.. "Synthesis, Characterization, and Reactivity of Oxomanganese(IV) Porphyrin Complexes". . p. 8628 - 8638. Retrieved 2007/10/02.