Dibenzo[B,D]furan-1-ylboronic acid

Base Information

• Chemical Name: Dibenzo[B,D]furan-1-ylboronic acid
• CAS No.: 162607-19-4
• Molecular Formula: C12H9BO3
• Molecular Weight: 212.00906
• European Community (EC) Number: 829-640-6
• DSSTox Substance ID: DTXSID801306837
• Nikkaji Number: J1.614.372C
• Mol file: 162607-19-4.mol

Synonyms:DIBENZO[B,D]FURAN-1-YLBORONIC ACID;162607-19-4;dibenzofuran-1-ylboronic acid;DIBENZOFURAN-1-BORONIC ACID;Dibenzo[b,d]furan-1-ylboronicacid;MFCD01318978;B-1-dibenzofuranylBoronic acid;dibenzofuran boronic acid;SCHEMBL1579938;Dibenzo[b,d]furan-1-boronic Acid;DTXSID801306837;AKOS027439921;AB08786;CS-16325;DA-20823;SY238336;CS-0095305;D5758;D70999;A852911;Dibenzofuran-1-boronic Acid (contains varying amounts of Anhydride);8-oxatricyclo[7.4.0.0(2),?]trideca-1(9),2(7),3,5,10,12-hexaen-3-ylboronic acid

Chemical Property of Dibenzo[B,D]furan-1-ylboronic acid

Chemical Property:

• Boiling Point: 438.5±37.0 °C(Predicted)
• PKA: 8.20±0.30(Predicted)
• PSA: 53.60000
• Density: 1.34±0.1 g/cm3(Predicted)
• LogP: 1.26580
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 212.0644743
• Heavy Atom Count: 16
• Complexity: 259

Purity/Quality:

99% ^*data from raw suppliers

Dibenzofuran-1-boronic Acid (contains varying amounts of Anhydride) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: B(C1=C2C3=CC=CC=C3OC2=CC=C1)(O)O
• Uses: 1-Dibenzofuranylboronic Acid is the reagent for electronic devices materials preparation. There are some synthesis routes to describe how do 1-dibenzofuranylboronic Acid works as the reagents for organic light emitting diode (OLED) applications.? 1-Dibenzofuranylboronic acid works as intermediate to synthesis the dibenzo [g, p] chrysene compound. Dibenzo[b,d]furan-1-ylboronic acid can be used as an intermediate in organic synthesis, mainly used in laboratory research and development and chemical production processes.

Technology Process of Dibenzo[B,D]furan-1-ylboronic acid

There total 16 articles about Dibenzo[B,D]furan-1-ylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-bromodibenzo[b,d]furan (50548-45-3) + Trimethyl borate (121-43-7,63156-11-6) → dibenzo[b,d]furan-1-yl-boronic acid (162607-19-4)

Guidance literature:

1-bromodibenzo[b,d]furan; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2.5h;

Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 18h;

Reference yield: 89.0%

1-bromodibenzo[b,d]furan (50548-45-3) + Trimethyl borate (121-43-7,63156-11-6) + water (7732-18-5) → dibenzo[b,d]furan-1-yl-boronic acid (162607-19-4)

Guidance literature:

1-bromodibenzo[b,d]furan; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

Trimethyl borate; In tetrahydrofuran;

water; With hydrogenchloride;

Reference yield: 77.0%

1-bromodibenzo[b,d]furan (50548-45-3) + Triisopropyl borate (5419-55-6) → dibenzo[b,d]furan-1-yl-boronic acid (162607-19-4)

Guidance literature:

1-bromodibenzo[b,d]furan; With n-butyllithium; In tetrahydrofuran; hexane; at -63 ℃; for 2.5h; Inert atmosphere;

Triisopropyl borate; In tetrahydrofuran; hexane; at -65 - 20 ℃; for 3.3h;

upstream raw materials:

1-bromodibenzo[b,d]furan

Triisopropyl borate

water

1-bromo-3-fluoro-2-iodo-benzene

Downstream raw materials:

dibenzo-[b,d]furan-4-carbonitrile

1-iododibenzo[b,d]furan

Refernces

• 1、 -. "NOVEL ORGANIC COMPOUND AND MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES COMPRISING THE SAME AND ORGANIC ELECTROLUMINESCENT DEVICES COMPRISING THE SAME". Paragraph 0152-0156. . Retrieved 2020/12/16.
• 2、 -. "NOVEL ORGANIC COMPOUND AND MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES COMPRISING THE SAME AND ORGANIC ELECTROLUMINESCENT DEVICES COMPRISING THE SAME". Paragraph 0122; 0262-0265. . Retrieved 2020/12/15.