Einecs 218-312-2

Base Information

• Chemical Name: Einecs 218-312-2
• CAS No.: 83808-03-1
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 178.231
• Mol file: 83808-03-1.mol

Synonyms:Ai3-20523;alpha-Ethylbenzyl alcohol acetate;Benzenemethanol, alpha-ethyl-, 1-acetate;Einecs 218-312-2

Chemical Property of Einecs 218-312-2

Chemical Property:

• PSA: 80.67000
• LogP: 3.16870

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Einecs 218-312-2

There total 115 articles about Einecs 218-312-2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-Phenyl-1-propanol (93-54-9) + acetic anhydride (108-24-7) → 1-phenylpropyl acetate (83808-03-1,2114-29-6) + dimethylglyoxal (431-03-8)

Guidance literature:

With cobalt(II) chloride; In acetonitrile; at 80 ℃; for 2h;

DOI:10.1021/jo00033a020

Reference yield: 91.0%

1-Phenyl-1-propanol (93-54-9) → 1-phenylpropyl acetate (83808-03-1,2114-29-6) + 1-phenyl-propan-1-one (93-55-0)

Guidance literature:

With dihydrogen peroxide; methyltrioxorhenium(VII); sodium bromide; In acetic acid; for 10h; Ambient temperature;

DOI:10.1021/jo9817164

Reference yield: 85.7%

ethyl acetate (141-78-6) + 1-phenyl-propan-1-one (93-55-0) → 1-phenylpropyl acetate (83808-03-1,2114-29-6) + 1-Phenyl-1-propanol (93-54-9)

Guidance literature:

With NaHB₄; for 15h; Heating;

DOI:10.1080/00397919108021569

upstream raw materials:

phenylpropane

1-Phenyl-1-propanol

lead(IV) tetraacetate

acetic acid

Downstream raw materials:

(R)-1-phenyl-1-propanol

(S)-1-phenyl-1-propanol

(R)-1-phenylpropyl acetate

(S)-1-phenylpropyl acetate

Refernces

• 1、 Murakami, Ryo,Suginome, Michinori,Yamamoto, Takeshi. "PQXdpap: Helical Poly(quinoxaline-2,3-diyl)s Bearing 4-(Dipropylamino)pyridin-3-yl Pendants as Chirality-Switchable Nucleophilic Catalysts for the Kinetic Resolution of Secondary Alcohols". supporting information. p. 8711 - 8716. Retrieved 2021/11/24.
• 2、 Chaubey, Snehkrishn A.,Mishra, Roli. "Synthesis of task-specific imidazolium ionic liquid as an efficient catalyst in acetylation of alcohols, phenols, and amines". . p. 3259 - 3268. Retrieved 2020/04/17.