Ytterbium iodide (YbI3)

Base Information

• Chemical Name: Ytterbium iodide (YbI3)
• CAS No.: 13813-44-0
• Molecular Formula: I3Yb
• Molecular Weight: 553.754
• European Community (EC) Number: 237-474-5
• DSSTox Substance ID: DTXSID0065648
• Wikipedia: Ytterbium(III) iodide
• Wikidata: Q2601503
• Mol file: 13813-44-0.mol

Synonyms:Ytterbium iodide (YbI3);13813-44-0;triiodoytterbium;Ytterbium triiodide;ytterbium(III) iodide;DTXSID0065648;EINECS 237-474-5;Q2601503

Chemical Property of Ytterbium iodide (YbI3)

Chemical Property:

• Melting Point: ~999 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.65710
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 554.6523
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%Min ^*data from raw suppliers

Ytterbium(II) iodide powder, ≥99.9% trace metals basis ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: I[Yb](I)I

Technology Process of Ytterbium iodide (YbI3)

There total 9 articles about Ytterbium iodide (YbI3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Yb(water)8](I)3 → ytterbium(III) iodide (13813-44-0)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Yb compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield:

iodine (7553-56-2,12190-71-5,8031-47-8) + ytterbium → ytterbium(III) iodide (13813-44-0)

Guidance literature:

In tetrahydrofuran; (N2); molar ratio of Yb:I2 2:3; clear THF soln. of triiodide obtained by filtration or decanting;

Reference yield:

[deca-phenyl ytterbocene] + iodine (7553-56-2,12190-71-5,8031-47-8) → ytterbium(III) iodide (13813-44-0)

Guidance literature:

In not given; byproducts: C5(C6H5)5;

DOI:10.1021/om800501z

upstream raw materials:

iodine

1,2-Diiodoethane

(Dichloroiodo)benzene

Downstream raw materials:

YbI(THF)2(Ph₂Si(N(2,6-iPr₂C₆H₃))2)

Refernces

• 1、 Huebner, Louise,Kornienko, Anna,Emge, Thomas J.,Brennan, John G.. "Heterometallic lanthanide Group 12 metal iodides". . p. 5659 - 5664. Retrieved 2004.
• 2、 Deacon, Glen B.,Forsyth, Craig M.,Jaroschik, Florian,Junk, Peter C.,Kay, Danielle L.,Maschmeyer, Thomas,Masters, Anthony F.,Wang, Jun,Field, Leslie D.. "Accessing decaphenylmetallocenes of ytterbium, calcium, and barium by desolvation of solvent-separated ion pairs: Overcoming adverse solubility properties". . p. 4772 - 4778. Retrieved 2009/02/08.