Technology Process of 3-O-benzyl laxogenin
There total 5 articles about 3-O-benzyl laxogenin which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
dipyridinium dichromate;
In
dichloromethane;
for 2h;
DOI:10.1021/jo980266c
- Guidance literature:
-
3-O-benzyl diosgenin;
With
dimethylsulfide borane complex;
In
tetrahydrofuran;
at 20 ℃;
for 12h;
With
sodium hydroxide; dihydrogen peroxide;
In
tetrahydrofuran; water;
at 20 ℃;
With
Dess-Martin periodane;
In
dichloromethane;
at 20 ℃;
for 5h;
Further stages.;
DOI:10.1021/jo026103c
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: NaH / tetrahydrofuran; dimethylformamide / 1 h / 20 °C
1.2: 97 percent / tetrahydrofuran; dimethylformamide / Heating
2.1: BH3*Me2S / tetrahydrofuran / 12 h / 20 °C
2.2: NaOH; H2O2 / tetrahydrofuran; H2O / 20 °C
2.3: 77 percent / Dess-Martin periodinane / CH2Cl2 / 5 h / 20 °C
With
dimethylsulfide borane complex; sodium hydride;
In
tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo026103c
