Technology Process of 6-O-benzoyl-6β-chlorogenin 3-O-(3,6-di-O-benzoyl-β-D-glucopyranoside)
There total 4 articles about 6-O-benzoyl-6β-chlorogenin 3-O-(3,6-di-O-benzoyl-β-D-glucopyranoside) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: methanol; sodium tetrahydroborate / 1,4-dioxane / 0 °C / Inert atmosphere
2: pyridine / 1 h / 0 °C / Inert atmosphere
3: palladium 10% on activated carbon; hydrogen; triethylamine / ethanol; dichloromethane / 12 h / 20 °C
4: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / -20 °C / Inert atmosphere; Molecular sieve
5: hydrazinium monoacetate / methanol; dichloromethane / 3 h / 20 °C / Inert atmosphere
With
pyridine; methanol; sodium tetrahydroborate; trimethylsilyl trifluoromethanesulfonate; palladium 10% on activated carbon; hydrogen; hydrazinium monoacetate; triethylamine;
In
1,4-dioxane; methanol; ethanol; dichloromethane;
DOI:10.1016/j.ejmech.2012.04.022
- Guidance literature:
-
Multi-step reaction with 3 steps
1: palladium 10% on activated carbon; hydrogen; triethylamine / ethanol; dichloromethane / 12 h / 20 °C
2: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / -20 °C / Inert atmosphere; Molecular sieve
3: hydrazinium monoacetate / methanol; dichloromethane / 3 h / 20 °C / Inert atmosphere
With
trimethylsilyl trifluoromethanesulfonate; palladium 10% on activated carbon; hydrogen; hydrazinium monoacetate; triethylamine;
In
methanol; ethanol; dichloromethane;
DOI:10.1016/j.ejmech.2012.04.022
- Guidance literature:
-
Multi-step reaction with 6 steps
1: Jones reagent / acetone / 0.33 h / 0 °C / Inert atmosphere
2: methanol; sodium tetrahydroborate / 1,4-dioxane / 0 °C / Inert atmosphere
3: pyridine / 1 h / 0 °C / Inert atmosphere
4: palladium 10% on activated carbon; hydrogen; triethylamine / ethanol; dichloromethane / 12 h / 20 °C
5: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / -20 °C / Inert atmosphere; Molecular sieve
6: hydrazinium monoacetate / methanol; dichloromethane / 3 h / 20 °C / Inert atmosphere
With
pyridine; methanol; sodium tetrahydroborate; Jones reagent; trimethylsilyl trifluoromethanesulfonate; palladium 10% on activated carbon; hydrogen; hydrazinium monoacetate; triethylamine;
In
1,4-dioxane; methanol; ethanol; dichloromethane; acetone;
DOI:10.1016/j.ejmech.2012.04.022