NSC47034

Base Information

• Chemical Name: NSC47034
• CAS No.: 6952-67-6
• Molecular Formula: C9H9NO4
• Molecular Weight: 195.175
• Hs Code.: 2932990090
• Mol file: 6952-67-6.mol

Synonyms:3-nitrophenyl-1,3-dioxolane;3-Nitrobenzaldehyde ethylene acetal;2-(3-Nitro-phenyl)-[1,3]dioxolane;3-nitrobenzyl ethylene acetal;

Chemical Property of NSC47034

Chemical Property:

• Vapor Pressure: 0.0011mmHg at 25°C
• Boiling Point: 310.4°Cat760mmHg
• Flash Point: 149.4°C
• PSA: 64.28000
• Density: 1.329g/cm³
• LogP: 2.16340
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

2-(3-Nitrophenyl)-1,3-dioxolane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of NSC47034

There total 8 articles about NSC47034 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3-nitro-benzaldehyde (99-61-6) → 3-aminobenzaldehyde ethylene acetal (6398-87-4) + 2-(3-nitrophenyl)-1,3-dioxolane (6952-67-6)

Guidance literature:

With toluene-4-sulfonic acid; In ethylene glycol; benzene;

Reference yield: 99.0%

3-nitro-benzaldehyde (99-61-6) + ethylene glycol (107-21-1) → 2-(3-nitrophenyl)-1,3-dioxolane (6952-67-6)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; Reflux; Dean-Stark;

DOI:10.1021/acs.joc.7b01161

Reference yield: 95.0%

3-nitro-benzaldehyde (99-61-6) → 2-(3-nitrophenyl)-1,3-dioxolane (6952-67-6)

Guidance literature:

With p-TsOH; In ethylene glycol; toluene;

upstream raw materials:

3-nitro-benzaldehyde

ethylene glycol

2-{[(3-nitrophenyl)methyl]oxy}ethanol

2-chloro-ethanol

Downstream raw materials:

3-aminobenzaldehyde ethylene acetal

2-(4-phenylsulfonylmethyl-5-nitrophenyl)-1,3-dioxolane

2-(2-phenylsulfonylmethyl-5-nitrophenyl)-1,3-dioxolane

2-/2-(1,3-doxolanyl)/-6-nitrobenzyl phenyl sulfone

Refernces

• 1、 Belokon, Yuri N.,Gak, Alexander,Khakina, Ekaterina,Khrustalev, Victor N.,Korlyukov, Alexander A.,Kuznetsova, Svetlana,Li, Han,Lobanov, Nikolai,Nelyubina, Yulia,North, Michael,Peregudov, Alexander S.,Riazanov, Vladimir,Zhereb, Vladimir. "Inhibition by Water during Heterogeneous Br?nsted Acid Catalysis by Three-Dimensional Crystalline Organic Salts". . p. 6364 - 6372. Retrieved 2021/10/20.
• 2、 Khaef, Sepideh,Taherpour, Avat Arman,Yarie, Meysam,Zolfigol, Mohammad Ali. "Catalytic application of sulfamic acid-functionalized magnetic Fe3O4nanoparticles (SA-MNPs) for protection of aromatic carbonyl compounds and alcohols: Experimental and theoretical studies". . p. 44946 - 44957. Retrieved 2020/12/30.