FORMIC ACID, 2-(o-NITROPHENYL)HYDRAZIDE

Base Information

• Chemical Name: FORMIC ACID, 2-(o-NITROPHENYL)HYDRAZIDE
• CAS No.: 60702-35-4
• Molecular Formula: C7H7 N3 O3
• Molecular Weight: 181.151
• Hs Code.: 2928000090
• DSSTox Substance ID: DTXSID70209523
• Nikkaji Number: J69.677C
• Wikidata: Q83083838
• Mol file: 60702-35-4.mol

Synonyms:FORMIC ACID, 2-(o-NITROPHENYL)HYDRAZIDE;BRN 1819666;60702-35-4;4-15-00-00309 (Beilstein Handbook Reference);N'-(o-Nitrophenyl)formhydrazide;SCHEMBL10551420;DTXSID70209523;AKOS006273388;N'-(2-NITROPHENYL)CARBOHYDRAZIDE;LS-69694

Chemical Property of FORMIC ACID, 2-(o-NITROPHENYL)HYDRAZIDE

Chemical Property:

• Boiling Point: 314oC at 760 mmHg
• Flash Point: 143.7oC
• PSA: 90.44000
• Density: 1.427g/cm3
• LogP: 2.10420
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 181.04874109
• Heavy Atom Count: 13
• Complexity: 192

Purity/Quality:

FORMIC ACID-2-(ORTHO-NITROPHENYL)HYDRAZIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)NNC=O)[N+](=O)[O-]

Technology Process of FORMIC ACID, 2-(o-NITROPHENYL)HYDRAZIDE

There total 4 articles about FORMIC ACID, 2-(o-NITROPHENYL)HYDRAZIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-Octadecanal (638-66-4) + (2-nitrophenyl)hydrazine (3034-19-3) → N-Formyl-N'-(o-nitrophenyl)hydrazine (60702-35-4)

Guidance literature:

n-Octadecanal; With 1,4-dihydronicotinamide adenine dinucleotide; Prochlorococcus marinus MIT₉₃₁₃ aldehyde decarbonylase; water; phenazine methosulfate; In dimethyl sulfoxide; at 37 ℃; for 0.5h;

(2-nitrophenyl)hydrazine; With pyridine; hydrogenchloride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In ethanol; water; at 65 ℃;

DOI:10.1002/anie.201101552

Reference yield:

formic acid (64-18-6) + (2-nitrophenyl)hydrazine (3034-19-3) → N-Formyl-N'-(o-nitrophenyl)hydrazine (60702-35-4)

Guidance literature:

DOI:10.1039/jr9550002326

Reference yield:

→ N-Formyl-N'-(o-nitrophenyl)hydrazine (60702-35-4)

Guidance literature:

With formic acid; sodium carbonate;

upstream raw materials:

formic acid

(2-nitrophenyl)hydrazine

n-Octadecanal

Downstream raw materials:

1,2,4-benzotriazene

2-Methyl-1H-benzimidazole

1,2-diamino-benzene

N-Formyl-N'-(o-aminophenyl)hydrazine

Refernces

• 1、 Chibani, A.,Hazard, R.,Tallec, A.. "Electrochemical reduction of o-nitrophenylhydrazides into 1,2,4-benzotriazines.". . p. 343 - 352. Retrieved 2007/10/02.