Ethylicin

Base Information

• Chemical Name: Ethylicin
• CAS No.: 682-91-7
• Molecular Formula: C4H10O2S2
• Molecular Weight: 154.254
• Hs Code.: 2930909051
• Mol file: 682-91-7.mol

Synonyms:Ethanesulfonicacid, thio-, S-ethyl ester (6CI,7CI,8CI);Ethanethiol, ethanesulfonate(6CI,8CI);Ethanethiosulfonic acid ethyl ester;Ethyl ethanethiosulfonate;NSC22422;Pseudoallicin 150;S-Ethyl ethanethiosulfonate;

Chemical Property of Ethylicin

Chemical Property:

• Vapor Pressure: 0.00533mmHg at 25°C
• Refractive Index: 1.488
• Boiling Point: 283.7 °C at 760 mmHg
• Flash Point: 125.4 °C
• PSA: 67.82000
• Density: 1.19 g/cm³
• LogP: 2.17000
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform

Purity/Quality:

99.9% ^*data from raw suppliers

Ethylicin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Ethylicin can be used for quick rooting powder special for figs.

Technology Process of Ethylicin

There total 5 articles about Ethylicin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

2,2-dimethyl-3,5-dithiaheptane (76229-69-1) → N-tert-butylacetamide (762-84-5) + ethyl ethanethiosulfonate (682-91-7)

Guidance literature:

With sodium perchlorate; In water; acetonitrile; anodic oxidation;

Reference yield: 3.0%

ethanesulfinyl chloride (1718-44-1) → Diethyl disulfide (110-81-6) + ethyl ethanethiosulfonate (682-91-7)

Guidance literature:

With zinc; In diethyl ether; 1.) 4 h, -20 deg C, 2.) 20 h, 22-24 deg C;

DOI:10.1055/s-1983-30564

Reference yield:

benzaldehyde diethyldithioacetal (7334-52-3) → ethyl ethanethiosulfonate (682-91-7) + benzaldehyde (100-52-7)

Guidance literature:

With sodium perchlorate; In water; acetonitrile; anodic oxidation;

upstream raw materials:

ethyl ethanethiosulfinate

ethanesulfinyl chloride

cyclohexanone-diethyldithioacetal

benzaldehyde diethyldithioacetal

Downstream raw materials:

1-ethylsulfanyl-1-(toluene-4-sulfonyl)-acetone

ethanesulfonyl-ethylsulfanyl-benzenesulfonyl-methane

diethyltrisulfane

ethanesulfonic acid

Refernces

• 1、 Porter, Quentin N.,Utley, James H. P.,Machion, Pedro D.,Pardini, Vera L.,Schumacher, Paolo R.,Viertler, Hans. "Electro-organic Reactions. Part 24. Preparative and Mechanistic Aspects of the Anodic Oxidation of Dithioacetals and 1,3-Dithianes". . p. 973 - 979. Retrieved 2007/10/02.
• 2、 Morishita, Tsuyoshy,Furukawa, Naomichi,Oae, Shigeru. "REACTION OF THIOLSULFINATES WITH TRIHALOACETIC ANHYDRIDES-I EVIDENCE FOR THE FORMATION OF SULFENYL AND SULFINYL CARBOXYLATES". . p. 3115 - 3120. Retrieved 2007/10/02.