bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene

Base Information

• Chemical Name: bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene
• CAS No.: 1426169-44-9
• Molecular Formula: C₄₈H₃₀Cl₂N₂
• Molecular Weight: 705.686
• Mol file: 1426169-44-9.mol

Synonyms:bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene

Chemical Property of bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene

There total 7 articles about bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

4-chloro-2,6-diphenylbenzenamine (203051-61-0) + acenaphthene quinone (82-86-0) → bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene (1426169-44-9)

Guidance literature:

With toluene-4-sulfonic acid; In benzene; for 24h; Inert atmosphere; Reflux;

DOI:10.1016/j.molcata.2013.01.016

Reference yield:

4-chloro-aniline (106-47-8) → bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene (1426169-44-9)

Guidance literature:

Multi-step reaction with 5 steps

1: dichloromethane / 0.5 h / Inert atmosphere

2: bromine / dichloromethane / 5 h / 5 °C / Inert atmosphere

3: sodium hydroxide / dichloromethane; water

4: palladium diacetate; potassium carbonate / 24 h / 25 °C / Inert atmosphere

5: toluene-4-sulfonic acid / benzene / 24 h / Inert atmosphere; Reflux

With bromine; palladium diacetate; potassium carbonate; toluene-4-sulfonic acid; sodium hydroxide; In dichloromethane; water; benzene; 4: |Suzuki Coupling;

DOI:10.1016/j.molcata.2013.01.016

Reference yield:

4-chloro-2,6-dibromoaniline (874-17-9) → bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene (1426169-44-9)

Guidance literature:

Multi-step reaction with 2 steps

1: palladium diacetate; potassium carbonate / 24 h / 25 °C / Inert atmosphere

2: toluene-4-sulfonic acid / benzene / 24 h / Inert atmosphere; Reflux

With palladium diacetate; potassium carbonate; toluene-4-sulfonic acid; In benzene; 1: |Suzuki Coupling;

DOI:10.1016/j.molcata.2013.01.016

upstream raw materials:

4-chloro-aniline

4-chloro-2,6-dibromoaniline

p-toluidine

phenylboronic acid

Downstream raw materials:

{bis[N,N'-(4-chloro-2,6-diphenylphenyl)imino]acenaphthene}dibromonickel

Refernces