1-Chloro-1,1,2,2,3,3-hexafluoropropane

Base Information

• Chemical Name: 1-Chloro-1,1,2,2,3,3-hexafluoropropane
• CAS No.: 422-55-9
• Molecular Formula: C3H Cl F6
• Molecular Weight: 186.484
• Hs Code.: 2903791090
• European Community (EC) Number: 207-015-3
• UNII: DKZ5SP3LRX
• DSSTox Substance ID: DTXSID0073906
• Nikkaji Number: J28.274J
• Wikidata: Q27276451
• Mol file: 422-55-9.mol

Synonyms:1-Chloro-1,1,2,2,3,3-hexafluoropropane;422-55-9;Propane, 1-chloro-1,1,2,2,3,3-hexafluoro-;BRN 1748898;DKZ5SP3LRX;UNII-DKZ5SP3LRX;EINECS 207-015-3;Hexafluorchlorpropan;C3HClF6;Propane, chlorohexafluoro-;SCHEMBL223407;DTXSID0073906;AKOS006275632;LS-119666;A7184;3-CHLORO-1,1,2,2,3,3-HEXAFLUOROPROPANE;Q27276451;28987-04-4

Chemical Property of 1-Chloro-1,1,2,2,3,3-hexafluoropropane

Chemical Property:

• Vapor Pressure: 813mmHg at 25°C
• Refractive Index: 1.2173 (estimate)
• Boiling Point: 23.1°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.521g/cm³
• LogP: 2.71840
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 185.9670967
• Heavy Atom Count: 10
• Complexity: 120

Purity/Quality:

99% ^*data from raw suppliers

1-Chloro-1,1,2,2,3,3-hexafluoropropane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(F)(F)Cl)(F)F)(F)F

Technology Process of 1-Chloro-1,1,2,2,3,3-hexafluoropropane

There total 13 articles about 1-Chloro-1,1,2,2,3,3-hexafluoropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

1,1,3-trichloro-2,2,3,3-tetrafluoropropane (422-54-8,134237-38-0) → 3-chloro-1,1,1,2,2,3-hexafluoropropane (422-57-1) + 1-chloro-1,1,2,2,3,3-hexafluoropropane (422-55-9) + 3,3-dichloro-1,1,1,2,2-pentafluoropropane (422-56-0) + 1,3-dichloro-1,1,2,2,3-pentafluoropropane (507-55-1)

Guidance literature:

With hydrogen fluoride; chromium(III) oxide; at 280 ℃;

DOI:10.1016/S0022-1139(00)82839-0

Reference yield:

2-chloro-1,1,2,2-tetrafluoroethane (354-25-6) → polytetrafluoroethylene (116-14-3,82785-14-6) + perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + trifluoromethan (75-46-7) + Chlorodifluoromethane (75-45-6) + 2,2,2-trifluoroethanol (420-46-2) + 1-chloro-1,1,2,2,3,3-hexafluoropropane (422-55-9) + perfluoroisobutylene (382-21-8) + 1,1,1,2-tetrafluoro-2-chloroethane (2837-89-0) + Octafluorocyclobutane (115-25-3)

Guidance literature:

at 642 - 780 ℃; Nickel-lined reactor Inconel 617; Pyrolysis;

Reference yield:

1,3-dichloro-1,1,2,2,3-pentafluoropropane (507-55-1) + 2,2-dichloro-1,1,1,3,3-pentafluoropropane (128903-21-9) → 1-chloro-1,1,2,2,3,3-hexafluoropropane (422-55-9) + 3,3-dichloro-1,1,1,2,2-pentafluoropropane (422-56-0) + 2,3,3-trichloro-1,1,1,2-tetrafluoropropane (422-47-9)

Guidance literature:

partially fluorinated aluminum oxide; at 300 ℃; for 10.0056h; Inert atmosphere;

upstream raw materials:

1,3-dichlorohexafluoropropane

Chlorodifluoromethane

1,1,3-trichloro-2,2,3,3-tetrafluoropropane

ethanol

Downstream raw materials:

polytetrafluoroethylene

perfluoropropylene

Chlorotrifluoroethylene

benzoyl-tert-butylnitroxyl radical

Refernces

• 1、 -. "Catalytical production processes for making hydrohalopropanes and hydrofluorobutanes". Page/Page column 3. . Retrieved 2008/06/13.
• 2、 Tanuma, T.,Ohnishi, K.,Okamoto, H.,Miyajima, T.,Morikawa, S.. "19F nuclear magnetic resonance studies of halogenated propanes". . p. 259 - 284. Retrieved 2007/10/02.