optically inactive bis-(trans-2-benzoylamino-cyclohexyl)-disulfide

Base Information

• Chemical Name: optically inactive bis-(trans-2-benzoylamino-cyclohexyl)-disulfide
• CAS No.: 10514-96-2
• Molecular Formula: C₂₆H₃₂N₂O₂S₂
• Molecular Weight: 468.684
• Mol file: 10514-96-2.mol

Synonyms:optically inactive bis-(trans-2-benzoylamino-cyclohexyl)-disulfide

Chemical Property of optically inactive bis-(trans-2-benzoylamino-cyclohexyl)-disulfide

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of optically inactive bis-(trans-2-benzoylamino-cyclohexyl)-disulfide

There total 6 articles about optically inactive bis-(trans-2-benzoylamino-cyclohexyl)-disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+/-)-trans-2-aminocyclohexanol (931-16-8,6850-38-0,6982-39-4,33092-82-9,38898-70-3,74111-21-0,108267-20-5,931-15-7) → optically inactive bis-(trans-2-benzoylamino-cyclohexyl)-disulfide (10514-96-2)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrachloromethane; chlorosulfuric acid / Erhitzen des Reaktionsprodukts mit wss. Natronlauge

2: ethanol; H₂S

3: oxygen / anschliessenden Benzoylierung

With tetrachloromethane; chlorosulphuric acid; ethanol; hydrogen sulfide; oxygen;

Reference yield:

2-cyclohexenylamine hydrochloride (22613-33-8) → optically inactive bis-(cis-2-benzoylamino-cyclohexyl)-disulfide (10514-96-2)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂S, P(OMe)3 / methanol / Irradiation

2: aq. NaOH

With sodium hydroxide; hydrogen sulfide; phosphorous acid trimethyl ester; In methanol;

DOI:10.1021/jo01055a030

Reference yield:

cis-2-amino-cyclohexanethiol (10514-92-8,10514-94-0,20509-06-2,23583-25-7) + benzoyl chloride (98-88-4) → optically inactive bis-(cis-2-benzoylamino-cyclohexyl)-disulfide (10514-96-2)

Guidance literature:

With sodium hydroxide;

DOI:10.1021/jo01055a030

upstream raw materials:

cis-2-amino-cyclohexanethiol

benzoyl chloride

2-cyclohexenylamine hydrochloride

trans-2-amino-1-cyclohexanethiol