Technology Process of DL-1,2-di-O-methyl-chiro-inositol
There total 6 articles about DL-1,2-di-O-methyl-chiro-inositol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tert.-butylhydroperoxide; osmium(VIII) oxide; tetraethylammonium acetate;
In
water; acetone;
Yields of byproduct given;
1.) 0 deg C, 1.5 h, 2.) RT, 3 d.;
DOI:10.1016/S0040-4020(01)81025-5
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 84 percent / DMAP / pyridine / 1.) 0 deg C, 2.5 h, 2.) RT
2: 73 percent / m-CPBA / CH2Cl2 / 22 h / Ambient temperature; pH 8 phosphate buffer
3: 100 percent / camphorsulfonic acid monohydrate / CHCl3 / 22.5 h / Ambient temperature
4: osmium tetroxide, N-methylmorpholino-N-oxide / 2-methyl-propan-2-ol; tetrahydrofuran; H2O / 84 h / Ambient temperature
With
dmap; osmium(VIII) oxide; camphor-10-sulfonic acid; 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; pyridine; dichloromethane; chloroform; water; tert-butyl alcohol;
DOI:10.1016/S0040-4020(01)81025-5
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 73 percent / m-CPBA / CH2Cl2 / 22 h / Ambient temperature; pH 8 phosphate buffer
2: 100 percent / camphorsulfonic acid monohydrate / CHCl3 / 22.5 h / Ambient temperature
3: osmium tetroxide, N-methylmorpholino-N-oxide / 2-methyl-propan-2-ol; tetrahydrofuran; H2O / 84 h / Ambient temperature
With
osmium(VIII) oxide; camphor-10-sulfonic acid; 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; dichloromethane; chloroform; water; tert-butyl alcohol;
DOI:10.1016/S0040-4020(01)81025-5
