D-PINITOL

Base Information

• Chemical Name: D-PINITOL
• CAS No.: 484-68-4
• Molecular Formula: C₇H₁₄O₆
• Molecular Weight: 194.185
• Mol file: 484-68-4.mol

Synonyms:(?à)-Pinitol; DL-Pinitol; NSC 43336;Pinitol; dl-Pinitol

Chemical Property of D-PINITOL

Chemical Property:

• Melting Point: 179-185 °C(lit.)
• Boiling Point: 317.2°Cat760mmHg
• PKA: 12.98±0.70(Predicted)
• Flash Point: 145.6°C
• PSA: 110.38000
• Density: 1.56g/cm³
• LogP: -3.18050

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of D-PINITOL

There total 49 articles about D-PINITOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4/6-O-methyl-myo-inositol 1,3,5-monoorthoformate → 4-O-methyl-myo-inositol (484-68-4,484-69-5,484-71-9,523-92-2,642-38-6,3559-00-0,3564-07-6,6090-97-7,7586-49-4,7600-53-5,10284-63-6,17405-65-1,22350-68-1,23887-12-9,32934-27-3,35688-46-1,56782-15-1,58769-21-4,60537-25-9,64314-40-5,74560-60-4,103773-59-7,111059-09-7,115888-70-5,144902-49-8)

Guidance literature:

With trifluoroacetic acid; at 20 ℃; for 5h;

DOI:10.1039/b417757f

Reference yield: 100.0%

DL-1,3-di-O-benzoyl-4-O-methyl-chiro-inositol (111015-74-8,138258-56-7) → 4-O-methyl-myo-inositol (484-68-4,484-69-5,484-71-9,523-92-2,642-38-6,3559-00-0,3564-07-6,6090-97-7,7586-49-4,7600-53-5,10284-63-6,17405-65-1,22350-68-1,23887-12-9,32934-27-3,35688-46-1,56782-15-1,58769-21-4,60537-25-9,64314-40-5,74560-60-4,103773-59-7,111059-09-7,115888-70-5,144902-49-8)

Guidance literature:

With water; triethylamine; In methanol; for 3h; Ambient temperature;

DOI:10.1016/S0040-4020(01)81025-5

Reference yield: 100.0%

DL-1,2-di-O-methyl-chiro-inositol (111015-73-7) → 4-O-methyl-myo-inositol (484-68-4,484-69-5,484-71-9,523-92-2,642-38-6,3559-00-0,3564-07-6,6090-97-7,7586-49-4,7600-53-5,10284-63-6,17405-65-1,22350-68-1,23887-12-9,32934-27-3,35688-46-1,56782-15-1,58769-21-4,60537-25-9,64314-40-5,74560-60-4,103773-59-7,111059-09-7,115888-70-5,144902-49-8)

Guidance literature:

With water; triethylamine; In methanol; for 3h; Ambient temperature;

DOI:10.1016/S0040-4020(01)81025-5

upstream raw materials:

quebrachitol

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

(4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one

1-O-Allyl-2,3,4-tri-O-benzyl-D-chiro-inositol

Downstream raw materials:

(1R,2S,3R,4R,5S,6S)-1-Methoxy-2,3,4,5,6-pentakis-trimethylsilanyloxy-cyclohexane

2,3,4,5,6-Penta-O-acetyl-1-O-methyl-myo-inositol

Refernces

• 1、 Jung, Pierre M. J.,Motherwell, William B.,Williams, Alvin S.. "Stereochemical observations on the bromate induced monobromopentahydroxylation of benzene by catalytic photoinduced charge transfer osmylation. A concise synthesis of (±)-pinitol". . p. 1283 - 1284. Retrieved 2007/10/03.
• 2、 Jaramillo,Martin-Lomas. "Approaches to the synthesis of glycosyl phosphatidyl inositols. Enantioselective synthesis of optically active chiro- and myo-inositols". . p. 2501 - 2504. Retrieved 2007/10/02.