Phenyltrimethylammonium hydroxide

Base Information

• Chemical Name: Phenyltrimethylammonium hydroxide
• CAS No.: 1899-02-1
• Molecular Formula: C9H14 N . H O
• Molecular Weight: 153.224
• Hs Code.: 29239000
• European Community (EC) Number: 217-592-3
• DSSTox Substance ID: DTXSID50883769
• Wikidata: Q27158311
• Mol file: 1899-02-1.mol

Synonyms:hydroxide of phenyltrimethylammonium;iodide of phenyltrimethylammonium;phenyltrimethylammonium;phenyltrimethylammonium acetate;phenyltrimethylammonium benzenesulfonate;phenyltrimethylammonium bromide;phenyltrimethylammonium chloride;phenyltrimethylammonium tosylate;phenyltrimethylammonium tribromide;phenyltrimethylammonium, tri(methyl-3(2)H)-labeled cpd;trimethyl-d9-anilinium hydroxide;trimethylanilinium;trimethylanilinium iodide;trimethylphenylammonium hydroxide;trimethylphenylammonium iodide;X-TractElute

Chemical Property of Phenyltrimethylammonium hydroxide

Chemical Property:

• Appearance/Colour: clear colorless solution
• Refractive Index: n20/D 1.395
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 23.06000
• Density: g/cm³
• LogP: 1.70650
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 153.115364102
• Heavy Atom Count: 11
• Complexity: 95.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trimethylphenylammonium Hydroxide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C,T,F
• Statements: 34-39/23/24/25-36/38-23/24/25-11
• Safety Statements: 26-36/37/39-45-36/37-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Quaternary Amines
• Canonical SMILES: C[N+](C)(C)C1=CC=CC=C1.[OH-]
• Uses: Trimethylanilinium hydroxide is the most common reagent in this type of organic ammonium salts.Other reagents used are tetramethylammonium hydroxide and m-(trifluoromethylphenyl)trimethylammonium hydroxide. the acetate salt and fluoride salt have also been reported.

Technology Process of Phenyltrimethylammonium hydroxide

There total 2 articles about Phenyltrimethylammonium hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyltrimethylammonium iodide (98-04-4) → trimethylphenylammonium hydroxide (1899-02-1)

Guidance literature:

With silver(l) oxide;

Reference yield:

aniline (62-53-3) → trimethylphenylammonium hydroxide (1899-02-1)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hydroxide; water

2: lead oxide; sulfuric acid / Zersetzen des gebildeten Sulfats mit Bariumhydroxyd

With potassium hydroxide; sulfuric acid; water; lead(II) oxide;

Reference yield: 94.0%

trimethylphenylammonium hydroxide (1899-02-1) + phenol (108-95-2,27073-41-2) → phenyltrimethylammonium phenoxide (17609-44-8)

Guidance literature:

With potassium carbonate; In methanol; at 20 ℃; for 24h; Molecular sieve;

DOI:10.1021/ol102539x

upstream raw materials:

phenyltrimethylammonium iodide

aniline

Downstream raw materials:

N-methyl-N-phenyltoluenesulfonamide

diethyl-(4-methoxy-3-nitro-benzyl)-amine

emetine

N,N-dimethyl-aniline