(+)-Butyl glycidyl ether

Base Information

• Chemical Name: (+)-Butyl glycidyl ether
• CAS No.: 121906-41-0
• Molecular Formula: C₇H₁₄O₂
• Molecular Weight: 130.187
• UNII: Y02A7LBH82
• Nikkaji Number: J2.358.512J
• Wikidata: Q27294088
• Mol file: 121906-41-0.mol

Synonyms:(2R)-2-(butoxymethyl)oxirane;(+)-Butyl glycidyl ether;121906-41-0;(+)-N-Butyl glycidyl ether;Butyl glycidyl ether, (+)-;(Butoxymethyl)oxirane, (R)-;Oxirane, (butoxymethyl)-, (R)-;UNII-Y02A7LBH82;Y02A7LBH82;1,2-Epoxy-3-butoxypropane;2beta-(Butoxymethyl)oxirane;SCHEMBL2632267;(2,3-Epoxypropyl)-butyl ether;EN300-784648;Q27294088

Chemical Property of (+)-Butyl glycidyl ether

Chemical Property:

• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 130.099379685
• Heavy Atom Count: 9
• Complexity: 73.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCOCC1CO1
• Isomeric SMILES: CCCCOC[C@H]1CO1

Technology Process of (+)-Butyl glycidyl ether

There total 15 articles about (+)-Butyl glycidyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

glycidyl n-butyl ether (2426-08-6) → poly(n-butyl glycidyl ether) + (R)-3-(Butoxy)-1,2-epoxypropane (2426-08-6,85858-60-2,121906-41-0,130232-96-1) + (S)-3-(Butoxy)-1,2-epoxypropane (121906-41-0)

Guidance literature:

C₆₄H₇₄Cl₂Co₂N₄O₄; bis(triphenylphosphoranylidene)-ammonium acetate; In toluene; at 0 ℃; for 1.06667h; Product distribution / selectivity;

Reference yield: 46.0%

glycidyl n-butyl ether (2426-08-6) → poly(n-butyl glycidyl ether) + (R)-3-(Butoxy)-1,2-epoxypropane (2426-08-6,85858-60-2,121906-41-0,130232-96-1) + (S)-3-(Butoxy)-1,2-epoxypropane (121906-41-0)

Guidance literature:

C₆₄H₇₄Cl₂Co₂N₄O₄; bis(triphenylphosphoranylidene)-ammonium acetate; In toluene; at 0 ℃; for 1.06667h; Product distribution / selectivity;

Reference yield: 45.0%

glycidyl n-butyl ether (2426-08-6) → (R)-3-(Butoxy)-1,2-epoxypropane (2426-08-6,85858-60-2,121906-41-0,130232-96-1)

Guidance literature:

With (R,R)-(-)-N,N′-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminocobalt(II); water; acetic acid; In diethyl ether; dichloromethane; at 0 - 20 ℃; for 20h; Schlenk technique;

DOI:10.1002/anie.201501729

upstream raw materials:

allyl n-butyl ether

glycidyl n-butyl ether

aniline

Downstream raw materials:

(S)-3-(3-fluorophenyl)-5-(hydroxymethyl)oxazolidin-2-one

(5R)-3-(3-fluorophenyl)-5-hydroxymethyloxazolidin-2-one

Refernces

• 1、 Solís-Mu?ana, Pablo,Salam, Joanne,Ren, Chloe Z.-J.,Carr, Bronte,Whitten, Andrew E.,Warr, Gregory G.,Chen, Jack L.-Y.. "An Amphiphilic (salen)Co Complex – Utilizing Hydrophobic Interactions to Enhance the Efficiency of a Cooperative Catalyst". supporting information. p. 3207 - 3213. Retrieved 2021/06/01.
• 2、 Xie, Shengming,Zhang, Junhui,Fu, Nan,Wang, Bangjin,Hu, Cong,Yuan, Liming. "Application of homochiral alkylated organic cages as chiral stationary phases for molecular separations by capillary gas chromatography". . . Retrieved 2016/12/03.