POLY(METHYL ACRYLATE)

Base Information

• Chemical Name: POLY(METHYL ACRYLATE)
• CAS No.: 9003-21-8
• Molecular Formula: C₄H₆O₂
• Molecular Weight: 86.0904
• Hs Code.: 32082010
• Mol file: 9003-21-8.mol

Synonyms:Acrylicacid methyl ester, polymers (8CI);Acrylic acid, methyl ester, homopolymer(6CI);705M;A 1;A 1 (acrylic polymer);Acrylic acid methyl ester polymer;Acryloid C 10LV;Actflow UMM 1001;Binder 705M;JN 33;MC 376;Methyl acrylatecopolymer;Methyl acrylate homopolymer;Methyl acrylate polymer;PA 1;PA 1(polymer);Paraloid C 10LV;Plexigum N 742;Poly(methyl acrylate);SK 9;SK 9(acrylic polymer);Summers SK 9;Texapret S;Viskol M;

Chemical Property of POLY(METHYL ACRYLATE)

Chemical Property:

• Appearance/Colour: clear liquid
• Melting Point: 110 °C
• Refractive Index: n20/D 1.494
• Boiling Point: 110 °C
• Flash Point: 40 °F
• PSA: 26.30000
• Density: 1.22g/mLat25°C
• LogP: 0.46480
• Storage Temp.: Flammables area

Purity/Quality:

98%,99%, ^*data from raw suppliers

Poly(methyl acrylate) solution average Mw ~40,000 by GPC ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn F
• Hazard Codes: F,Xn
• Statements: 11-38-48/20-63-65-67
• Safety Statements: 36/37-46-62-16

MSDS Files:

SDS file from LookChem

Useful:

• Uses: PMA/methylamine borane (MeAB) composites, prepared by solution blending process finds uses as a hydrogen storage material with better dehydrogenation property compared to MeAB.

Technology Process of POLY(METHYL ACRYLATE)

There total 223 articles about POLY(METHYL ACRYLATE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.5%

methanol (67-56-1) + acrolein (107-02-8,25068-14-8) → 3,3-dimethoxyprop-1-ene (6044-68-4) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3)

Guidance literature:

With oxygen; Pd₅-Bi₂-Fe₁/⁽¹⁰⁰⁾SiO₂-MgO; for 4h;

Reference yield: 45.0%

methanol (67-56-1) + acetic acid (64-19-7,77671-22-8) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + acetic acid methyl ester (79-20-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + acrylic acid (79-10-7)

Guidance literature:

With oxygen; V-Ti-P oxide; at 390 ℃; Product distribution; other temperatures, various oxygen and methanol concentrations;

DOI:10.1246/bcsj.63.199

Reference yield: 42.0%

methanol (67-56-1) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + acetaldehyde (75-07-0,9002-91-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + acetone (67-64-1) + acrylic acid (79-10-7)

Guidance literature:

With oxygen; CoMoTeO; V-W-Mo-O; silica gel; In gas; at 360 ℃; Product distribution; two catalytic beds - one reactor; other catalysts (Ni-Co-Fe-Bi-K-P-Mo-O/SiO₂, etc.); effect of the composition of the gas mixture (propene/air, propene/air/water, methanol/nitrogen, methanol/air);

upstream raw materials:

methanol

formaldehyd

acetic acid methyl ester

3-Methoxypropionic acid

Downstream raw materials:

4-(2-methoxycarbonyl-ethylamino)-benzoic acid ethyl ester

5-exo-methoxycarbonylbicyclo<2.2.2>oct-2-ene

methyl endo-bicyclo<2.2.2>oct-5-ene-2-carboxylate

bis-[2-(2-methoxycarbonyl-ethyl)-cyclohexylidene]-hydrazine

Refernces

• 1、 Zhang, Jinquan,Zhang, Shuaizhong,Zou, Hongbin. "Acid- And base-switched palladium-catalyzed γ-C(sp3)-H alkylation and alkenylation of neopentylamine". supporting information. p. 3466 - 3471. Retrieved 2021/05/31.
• 2、 Li, Xiaopei,Kato, Tatsuhisa,Nakamura, Yasuyuki,Yamago, Shigeru. "The effect of viscosity on the coupling and hydrogen-abstraction reaction between transient and persistent radicals". . p. 966 - 972. Retrieved 2021/04/29.