Fluoroethane

Base Information

• Chemical Name: Fluoroethane
• CAS No.: 353-36-6
• Molecular Formula: C2H5F
• Molecular Weight: 48.0601
• Hs Code.: 2903399090
• European Community (EC) Number: 206-531-6
• UN Number: 2453
• UNII: XO7SPI984C
• DSSTox Substance ID: DTXSID2059857
• Nikkaji Number: J2.578J
• Wikipedia: Fluoroethane
• Wikidata: Q3074512,Q83073073
• Mol file: 353-36-6.mol

Synonyms:FLUOROETHANE;Ethane, fluoro-;Ethyl fluoride;353-36-6;Monofluoroethane;HFC-161;C2H5F;HFC 161;R 161;EINECS 206-531-6;UN2453;UNII-XO7SPI984C;BRN 1730748;XO7SPI984C;Ethylfluoride;CH2CH2F;fluoranylethane;Etano, fluoro-;1-Fluoroethane #;FCH2CH2;DTXSID2059857;C2-H5-F;HFA-161;MFCD00039284;NA2453;AKOS006228785;UN 2453;Ethyl fluoride or Refrigerant gas R161;LS-65568;F-161;FT-0626476;R-161;A822739;Q3074512;Ethyl fluoride or Refrigerant gas R161 [UN2453] [Flammable gas];Ethyl fluoride or Refrigerant gas R161 [UN2453] [Flammable gas]

Chemical Property of Fluoroethane

Chemical Property:

• Vapor Pressure: 5970mmHg at 25°C
• Melting Point: -143,2°C
• Refractive Index: 1.3057 (589.3 nm -40℃)
• Boiling Point: -37,1°C
• PSA: 0.00000
• Density: 0.717 g/cm³
• LogP: 0.97580
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 48.037528322
• Heavy Atom Count: 3
• Complexity: 2.8
• Transport DOT Label: Flammable Gas

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F
• Statements: R12:Extremely flammable.
• Safety Statements: S16:Keep away from sources of ignition - No smoking.; S23:Do not inhale gas/fumes/vapour/spray.; S9:Keep container

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Solvents -> Chlorofluorocarbons
• Canonical SMILES: CCF

Technology Process of Fluoroethane

There total 54 articles about Fluoroethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.7%

triethyloxonium tris(pentafluoroethyl)trifluorophosphate (945614-32-4) + 1-ethyl-3-methylimidazolium hexafluorophosphate (155371-19-0) → 1-ethyl-3-methyl-imidazolium tris(pentafluoroethyl)trifluorophosphate (377739-43-0) + diethyl ether (60-29-7,927820-24-4) + 1-fluoroethane (353-36-6) + phosphorus pentafluoride (7647-19-0,874483-74-6)

Guidance literature:

at 100 ℃; for 10h; Product distribution / selectivity;

Reference yield: 90.3%

triethyloxonium tris(pentafluoroethyl)trifluorophosphate (945614-32-4) + 1-ethyl-3-methylimidazolium tetrafluoroborate (143314-16-3) → 1-ethyl-3-methyl-imidazolium tris(pentafluoroethyl)trifluorophosphate (377739-43-0) + diethyl ether (60-29-7,927820-24-4) + 1-fluoroethane (353-36-6) + boron trifluoride (7637-07-2)

Guidance literature:

at 100 ℃; for 10h; Product distribution / selectivity;

Reference yield: 57.5%

ethoxyflurane (310-71-4) → 1-fluoroethane (353-36-6) + chloroethane (75-00-3) + chlorofluoroacetyl fluoride (359-34-2) + chlorofluoroacetyl chloride (359-32-0)

Guidance literature:

With aluminium trichloride; for 1.58333h;

DOI:10.1016/S0022-1139(00)82333-7

upstream raw materials:

ethyl bromide

ethanol

ethane

ethene

Downstream raw materials:

monofluoroethyl bromide

1-ethoxy-perfluoropropane

hydrogen fluoride

triethyloxonium fluoroborate

Refernces

• 1、 Kerr et al.. "". . p. 365. Retrieved 1967.
• 2、 Ishikawa,Arai. "VIBRATIONAL LEVEL POPULATIONS OF HYDROGEN FLUORIDE PRODUCED IN INFRARED MULTIPLE-PHOTON DECOMPOSITION OF C2H5F.". . p. 2040 - 2045. Retrieved 1984.
• 3、 Barlow, Michael G.,Haszeldine, Robert N.,Peck, Colin J.. "Hexafluoro-3-oxatricyclo2,4>hept-6-ene (Hexafluoro-Dewar-benzene Oxide) from the Photochemical Oxidation of Hexafluorobenzene". . p. 158 - 159. Retrieved 1980.
• 4、 Gontar',A.F. et al.. "". . . Retrieved 1977.
• 5、 Alyev et al.. "". . p. 2469. Retrieved 1976.
• 6、 Zhao, Shu-Bin,Becker, Jennifer J.,Gagne, Michel R.. "Steric crowding makes challenging Csp3 - F reductive eliminations feasible". scheme or table. p. 3926 - 3929. Retrieved 2011/10/03.