diethyl phosphorochloridodithioite

Base Information

• Chemical Name: diethyl phosphorochloridodithioite
• CAS No.: 1486-42-6
• Molecular Formula: C₄H₁₀ClPS₂
• Molecular Weight: 188.682
• Mol file: 1486-42-6.mol

Synonyms:diethyl phosphorochloridodithioite

Chemical Property of diethyl phosphorochloridodithioite

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl phosphorochloridodithioite

There total 14 articles about diethyl phosphorochloridodithioite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

S,S-diethyl-N-diethylamidodithiophosphite (42964-63-6) + benzoyl chloride (98-88-4) → diethyl phosphorochloridodithioite (1486-42-6) + N,N-diethylbenzamide (1696-17-9)

Guidance literature:

Product distribution; -40 deg C to room temperature, then 1 h;

Reference yield: 89.0%

O-acetyl S,S-diethyl phosphorodithioite (84103-76-4) → diethyl phosphorochloridodithioite (1486-42-6) + acetic anhydride (108-24-7)

Guidance literature:

With acetyl chloride; for 0.5h; Ambient temperature;

Reference yield: 89.0%

O-acetyl S,S-diethyl phosphorodithioite (84103-76-4) + acetyl chloride (75-36-5) → diethyl phosphorochloridodithioite (1486-42-6) + acetic anhydride (108-24-7)

Guidance literature:

at 20 ℃; for 0.5h;

DOI:10.1007/BF00954199

upstream raw materials:

triethyl trithiophosphite

benzyl chloride

acetyl chloride

S,S,S-triethyl phosphorotrithioate

Downstream raw materials:

ethyl dichlorothiophosphite

ethyl thioacetate

Cyclohexyl-isopropyl-dithiophosphoramidic acid diethyl ester

(4-Methyl-cyclohexyl)-dithiophosphoramidic acid diethyl ester

Refernces

• 1、 Sinyashin, O. G.,Zubanov, V. A.,Pozdeev, O. K.,Gil'manova, G. Kh.,Batyeva, E. S.,Pudovik, A. N.. "REACTIONS OF PHOSPHORUS(III) THIO ESTERS WITH SUBSTITUTED 1-CHLOROACETYLENES. N,N,N',N'-TETRAALKYL-P-ETHYNYLPHOSPHONOTHIOIC DIAMIDES WITH ANTIVIRAL ACTIVITY". . p. 1102 - 1108. Retrieved 2007/10/02.
• 2、 Sinyashin, O. G.,Karimullen, Sh. A.,Batyeva, E. S.,Pudovik, A. N.. "RETENTION OF COORDINATION NUMBER OF PHOSPHORUS IN REACTIONS OF PHOSPHOROTRITHIOUS ESTERS WITH CARBON TETRACHLORIDE". . p. 401 - 402. Retrieved 2007/10/02.