N,N'-Dinitroethylenediamine

Base Information

• Chemical Name: N,N'-Dinitroethylenediamine
• CAS No.: 505-71-5
• Molecular Formula: C2H6 N4 O4
• Molecular Weight: 150.094
• Hs Code.: 2928000090
• European Community (EC) Number: 208-018-2
• NSC Number: 77355
• UNII: O5GD93K6WK
• DSSTox Substance ID: DTXSID3052141
• Wikipedia: Ethylenedinitramine
• Wikidata: Q4532975
• Mol file: 505-71-5.mol

Synonyms:EDNA cpd;ethylenedinitramine

Chemical Property of N,N'-Dinitroethylenediamine

Chemical Property:

• Melting Point: 175.25°C
• Refractive Index: 1.6000 (estimate)
• Boiling Point: 335.9°Cat760mmHg
• Flash Point: 157°C
• PSA: 115.70000
• Density: 1.432g/cm³
• LogP: 0.37720
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 150.03890469
• Heavy Atom Count: 10
• Complexity: 108

Purity/Quality:

99% ^*data from raw suppliers

N,N'-DINITRO ETHYLENE DIAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(CN[N+](=O)[O-])N[N+](=O)[O-]

Technology Process of N,N'-Dinitroethylenediamine

There total 21 articles about N,N'-Dinitroethylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1,3-dinitroimidazolidin-2-one (2536-18-7) → 1,4-dinitro-1,4-diazabutane (505-71-5)

Guidance literature:

With water; at 100 ℃; for 0.0833333h;

DOI:10.1021/acs.inorgchem.0c03752

Reference yield: 63.0%

N-hydroxymethylethylenedinitroamine (10120-27-1) → 1,4-dinitro-1,4-diazabutane (505-71-5)

Guidance literature:

With water; Heating;

Reference yield: 55.0%

imidazolidone (120-93-4) → 1,4-dinitro-1,4-diazabutane (505-71-5)

Guidance literature:

With nitric acid; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/chem.201501721

upstream raw materials:

tetra-N-chloro-ethylenediamine

N-(2-formylaminoethyl)formamide

N,N'-dinitro-N,N'-ethanediyl-bis-acetamide

N,N'-dinitro-N,N'-ethane-1,2-diylbis(carbamic acid) diethyl ester

Downstream raw materials:

N-methyl-N,N'-dinitroethylenediamine

2,5-dinitro-2,5-diazahexane

ethylene glycol

water

Refernces

• 1、 Gruhne, Michael S.,Lommel, Marcus,Wurzenberger, Maximilian H. H.,Klap?tke, Thomas M.,Stierstorfer, J?rg. "Investigation of Ethylenedinitramine as a Versatile Building Block in Energetic Salts, Cocrystals, and Coordination Compounds". supporting information. p. 4816 - 4828. Retrieved 2021/04/09.
• 2、 Zharkov, Mikhail N.,Kuchurov, Ilya V.,Fomenkov, Igor V.,Tartakovsky, Vladimir A.,Fedyanin, Ivan V.,Zlotin, Sergei G.. "Safe and Convenient Synthesis of Primary N -Nitramines in the Freon Media". supporting information. p. 1103 - 1108. Retrieved 2017/02/24.