N-(2-ForMaMidoethyl)forMaMid

Base Information

• Chemical Name: N-(2-ForMaMidoethyl)forMaMid
• CAS No.: 4938-92-5
• Molecular Formula: C4H8N2O2
• Molecular Weight: 116.12
• Hs Code.: 2924199090
• Mol file: 4938-92-5.mol

Synonyms:1,2-ethanyl-bis-formamide;N,N'-1,2-ethanediylbisformamide;formamide,n,n'-1,2-ethanediylbis;N,N'-ethane-1,2-diyldiformamide;N1,N2-diformylethylenediamine;NN'-diformyl-1,2-diaminoethane;

Chemical Property of N-(2-ForMaMidoethyl)forMaMid

Chemical Property:

• Boiling Point: 478.7°Cat760mmHg
• Flash Point: 250.2°C
• PSA: 58.20000
• Density: 1.086g/cm³
• LogP: 0.53200

Purity/Quality:

99%min ^*data from raw suppliers

N,N''-Ethylene-bis(formamide) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of N-(2-ForMaMidoethyl)forMaMid

There total 4 articles about N-(2-ForMaMidoethyl)forMaMid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

N-(2-aminoethyl)formamide (69219-13-2) → imidazolidone (120-93-4) + N-(2-formylaminoethyl)formamide (4938-92-5)

Guidance literature:

With [Ru(P^tBuNNH^tBu)H(CO)Cl]; potassium tert-butylate; In 1,4-dioxane; at 150 ℃; for 24h; Glovebox; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.201901695

Reference yield: 13.8%

carbon dioxide (124-38-9,18923-20-1) + ethylenediamine (107-15-3,85404-18-8) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → imidazolidone (120-93-4) + N-(2-formylaminoethyl)formamide (4938-92-5)

Guidance literature:

With ZnO-KF loaded on γ-Al₂O₃ ; at 180 ℃; for 4h; under 7500.75 Torr;

DOI:10.1016/j.apcata.2020.117550

Reference yield:

N,N'-ethylenethiourea (96-45-7) + methanol (67-56-1) → N-(2-formylaminoethyl)formamide (4938-92-5) + ethylenediamine (107-15-3,85404-18-8)

Guidance literature:

upstream raw materials:

N,N'-ethylenethiourea

methanol

ethylenediamine

N-(2-aminoethyl)formamide

Downstream raw materials:

1,4-dinitro-1,4-diazabutane

formic acid

ethylenediamine

N,N'-diformyl-N,N'-1,2-ethanediylbisbenzamide

Refernces

• 1、 Xie, Yinjun,Hu, Peng,Ben-David, Yehoshoa,Milstein, David. "A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea". supporting information. p. 5105 - 5109. Retrieved 2019/03/11.