Phenyltin(3+);trichloride

Base Information

• Chemical Name: Phenyltin(3+);trichloride
• CAS No.: 1124-19-2
• Molecular Formula: C6H5Cl3Sn
• Molecular Weight: 302.175
• Hs Code.: 29319090
• Mol file: 1124-19-2.mol

Synonyms:AKOS025402694;P1282

Chemical Property of Phenyltin(3+);trichloride

Chemical Property:

• Appearance/Colour: Clear colorless liquid,darkening on light exposure
• Vapor Pressure: 0.0233mmHg at 25°C
• Melting Point: -31 °C
• Refractive Index: n20/D 1.585(lit.)
• Boiling Point: 257.5 °C at 760 mmHg
• Flash Point: 109.6 °C
• PSA: 0.00000
• Density: 1.839 g/mL at 25 °C(lit.)
• LogP: 2.54890
• Storage Temp.: Dark Room
• Sensitive.: Moisture Sensitive
• Water Solubility.: Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 301.847886
• Heavy Atom Count: 10
• Complexity: 46.1

Purity/Quality:

99.0% ^*data from raw suppliers

Phenyltin trichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn+3].[Cl-].[Cl-].[Cl-]
• Uses: Phenyltin trichloride is used to produce 3-phenyl-cyclohexanone with cyclohex-2-enone. And it is also used in pharmaceutical intermediates.

Technology Process of Phenyltin(3+);trichloride

There total 31 articles about Phenyltin(3+);trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

triphenyllead(IV) chloride (1153-06-6) + tin(IV) chloride (7646-78-8) → phenyltin trichloride (1124-19-2)

Guidance literature:

In chloroform-d1; at 20 ℃; for 0.2h; Sealed tube; Inert atmosphere;

DOI:10.1039/c7dt04520d

Reference yield: 80.0%

1,8-bis(triphenylstannyl)octane (87518-43-2) + tin(IV) chloride (7646-78-8) → 1,8-bis(trichlorostannyl)octane (351387-99-0) + phenyltin trichloride (1124-19-2)

Guidance literature:

In neat (no solvent); heating for 3 h at 120-130°C; the mixt. was distd. in vac.; elem. anal.;

DOI:10.1021/om010202j

Reference yield: 76.0%

dichloro(ethyl)phenylsilane (1125-27-5,18447-29-5) + tin(IV) chloride (7646-78-8) → phenyltin trichloride (1124-19-2)

Guidance literature:

With AlCl₃; In neat (no solvent); byproducts: C2H5SiCl3; heated at 110-145°C for 9 h; AlCl3 filtered off; filtrate distd.;

upstream raw materials:

tetraphenyltin(IV)

boron trichloride

diphenyltin(IV) dichloride

antimonypentachloride

Downstream raw materials:

biphenyl-4-acetaldehyde

4-Methylbiphenyl

p-phenylpyridine

3-phenylcyclohexanone

Refernces

• 1、 Arias-Ugarte, Renzo N.,Pannell, Keith H.. "A utility for organoleads: Selective alkyl and aryl group transfer to tin". . p. 1703 - 1708. Retrieved 2018/02/09.
• 2、 Zobel, Bernhard,Duthie, Andrew,Dakternieks, Dainis,Tiekink, Edward R.T.. "αω-bis(trichlorostannyl)alkanes: Unravelling the hydrolysis pathway to organotin-oxo oligomers". . p. 2820 - 2826. Retrieved 2008/10/08.