sec-butylnitrate

Base Information

• Chemical Name: sec-butylnitrate
• CAS No.: 924-52-7
• Molecular Formula: C4H9NO3
• Molecular Weight: 119.12
• Hs Code.: 2920909090
• Mol file: 924-52-7.mol

Synonyms:Nitric acid, 1-methylpropyl ester;2--butyl nitrate;nitric acid sec-butyl ester;Butane-2-nitrate;2-nitrooxy-butane;Salpetersaeure-sec-butylester;sec-Butyl Nitrate;Nitric acid,1-methylpropyl ester;

Chemical Property of sec-butylnitrate

Chemical Property:

• Vapor Pressure: 15.5mmHg at 25°C
• Melting Point: -111.59°C (estimate)
• Refractive Index: 1.4015
• Boiling Point: 124.3°Cat760mmHg
• Flash Point: 40.9°C
• PSA: 55.05000
• Density: 1.044g/cm³
• LogP: 1.51640

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sec-butylnitrate

There total 9 articles about sec-butylnitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butane (106-97-8,9003-29-6,9021-92-5) → n-Butyl nitrite (544-16-1) + butyl nitrate (928-45-0) + sec-butyl nitrite (924-43-6) + 2-nitrobutane (600-24-8,116783-22-3) + 2-butyl nitrate (924-52-7) + 1-nitrobutane (627-05-4)

Guidance literature:

With dihydrogen peroxide; Nitrogen dioxide; at 24.9 ℃; under 300.02 Torr; Rate constant; Product distribution; Mechanism; boric-acid-coated surface; various pressure and carrier-gas composition;

DOI:10.1039/f19848000609

Reference yield:

n-butane (106-97-8,9003-29-6,9021-92-5) → ethyl nitrate (625-58-1) + butyl nitrate (928-45-0) + 2-butyl nitrate (924-52-7) + peroxyacetyl nitrate (2278-22-0) + peroxy-n-butyryl nitrate (27746-48-1) + butanone (78-93-3)

Guidance literature:

With air; Nitrogen dioxide; at 25 ℃; for 6h; Product distribution; Mechanism; Kinetics; Irradiation; also addition of NO;

DOI:10.1007/PL00010127

Reference yield:

2-butyl iodide (513-48-4,52152-71-3) → 2-nitrobutane (600-24-8,116783-22-3) + 2-butyl nitrate (924-52-7)

Guidance literature:

With silver(I) nitrite;

upstream raw materials:

2-butyl iodide

n-butane

1-bromo-butane

Nitroethane

Downstream raw materials:

iso-butanol

Refernces

• 1、 Evmorfopoulou, Efthalia,Glavas, Sotirios. "Formation of nitrogenous compounds in the photooxidation of n-butane under atmospheric conditions". . p. 1151 - 1159. Retrieved 2007/10/03.
• 2、 Baulch, Donald L.,Campbell, Ian M.,Chappel, Jonathan M.. "Formation of Organic Nitro-compounds in Flowing H2O2+NO2+N2+Organic Vapour Systems. Part 3.-Effects of O2 Addition on H2O2+NO2+N2+Alkane Systems". . p. 617 - 628. Retrieved 2007/10/02.