sec-Butyl nitrite

Base Information

• Chemical Name: sec-Butyl nitrite
• CAS No.: 924-43-6
• Deprecated CAS: 132910-26-0
• Molecular Formula: C4H9 N O2
• Molecular Weight: 103.121
• Hs Code.: 2920909090
• European Community (EC) Number: 213-104-8
• DSSTox Substance ID: DTXSID90862472
• Nikkaji Number: J34.586E
• Mol file: 924-43-6.mol

Synonyms:sec-butyl nitrite

Chemical Property of sec-Butyl nitrite

Chemical Property:

• Vapor Pressure: 140mmHg at 25°C
• Refractive Index: 1.3710
• Boiling Point: 70.5°Cat760mmHg
• Flash Point: °C
• PSA: 38.66000
• Density: 0.99g/cm³
• LogP: 1.48290
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 103.063328530
• Heavy Atom Count: 7
• Complexity: 55.7

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 11-20/22
• Safety Statements: 16-24-46

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(C)ON=O

Technology Process of sec-Butyl nitrite

There total 14 articles about sec-Butyl nitrite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butane (106-97-8,9003-29-6,9021-92-5) → n-Butyl nitrite (544-16-1) + butyl nitrate (928-45-0) + sec-butyl nitrite (924-43-6) + 2-nitrobutane (600-24-8,116783-22-3) + 2-butyl nitrate (924-52-7) + 1-nitrobutane (627-05-4)

Guidance literature:

With dihydrogen peroxide; Nitrogen dioxide; at 24.9 ℃; under 300.02 Torr; Rate constant; Product distribution; Mechanism; boric-acid-coated surface; various pressure and carrier-gas composition;

DOI:10.1039/f19848000609

Reference yield:

iso-butanol (78-92-2,15892-23-6) → (R)-Octan-2-ol (5978-70-1,113301-48-7,4128-32-9) + sec-butyl nitrite (924-43-6)

Guidance literature:

Reference yield:

s-butyl bromide (78-76-2,5787-31-5) → sec-butyl nitrite (924-43-6) + 2-nitrobutane (600-24-8,116783-22-3)

Guidance literature:

With silver(I) nitrite; unter Kuehlung;

upstream raw materials:

s-butyl bromide

2-butyl iodide

iso-butanol

n-butane

Downstream raw materials:

methane

trans-nitrosomethane dimer

butanone

iso-butanol

Refernces

• 1、 Kawakami, Norifumi,Shoji, Osami,Watanabe, Yoshihito. "Use of perfluorocarboxylic acids to trick cytochrome P450BM3 into initiating the hydroxylation of gaseous alkanes". supporting information; experimental part. p. 5315 - 5318. Retrieved 2011/07/09.
• 2、 Jin, Jin,Sioutis, Ilias,Tarczay, Gyoergy,Gopalakrishnan, Sandhya,Bezant, Andrew,Miller, Terry A.. "Dispersed fluorescence spectroscopy of primary and secondary alkoxy radicals". . p. 11780 - 11797. Retrieved 2008/01/27.