(1-n-heptylallyl)chloropalldium dimer

Base Information

• Chemical Name: (1-n-heptylallyl)chloropalldium dimer
• CAS No.: 74417-84-8
• Molecular Formula: C₂₀H₃₈Cl₂Pd₂
• Molecular Weight: 562.268
• Mol file: 74417-84-8.mol

Synonyms:(1-n-heptylallyl)chloropalldium dimer

Chemical Property of (1-n-heptylallyl)chloropalldium dimer

Chemical Property:

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Technology Process of (1-n-heptylallyl)chloropalldium dimer

There total 1 articles about (1-n-heptylallyl)chloropalldium dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

cis-bis(acetonitrile)chloronitropalladium(II) (91547-45-4) + 1-Decene (872-05-9,17438-89-0,25189-70-2) → 1,2-Epoxydecane (2404-44-6) + (1-n-heptylallyl)chloropalldium dimer (74417-84-8) + Decan-2-one (693-54-9)

Guidance literature:

With oxygen; In toluene; toluene, 25-85°C, 0.5-24 h, air;; evapd., flash chromy.;;

DOI:10.1021/om00090a001

Reference yield: 67.1%

(1-n-heptylallyl)chloropalldium dimer (74417-84-8) + N-benzyl-1,1,1-trifluoromethanesulfonamide (36457-58-6) → (E)-N-benzyl-N-(dec-2-en-1-yl)-1,1,1-trifluoromethanesulfonamide

Guidance literature:

(1-n-heptylallyl)chloropalldium dimer; With silver(I) acetate; In chloroform-d1; at 45 ℃; for 0.166667h; Inert atmosphere;

With C₁₉H₂₁NO₃S; In chloroform-d1; at 45 ℃; for 0.166667h; Inert atmosphere;

N-benzyl-1,1,1-trifluoromethanesulfonamide; In chloroform-d1; at 45 ℃; for 2h; stereoselective reaction; Inert atmosphere;

DOI:10.1021/jacs.7b13492

upstream raw materials:

cis-bis(acetonitrile)chloronitropalladium(II)

1-Decene

Refernces