1-Decene

Base Information

• Chemical Name: 1-Decene
• CAS No.: 872-05-9
• Deprecated CAS: 108778-38-7,105054-87-3,122525-37-5,157185-82-5,215723-62-9,221043-31-8,330625-93-9,330625-94-0,375348-80-4,182876-33-1
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• Hs Code.: 29012980
• European Community (EC) Number: 212-819-2,682-116-7
• ICSC Number: 1477
• NSC Number: 62122
• UN Number: 3295,1993
• UNII: 7O4U4C718P
• DSSTox Substance ID: DTXSID8027329
• Nikkaji Number: J43.300D
• Wikipedia: Decene
• Wikidata: Q151410
• Metabolomics Workbench ID: 5009
• ChEMBL ID: CHEMBL3187990
• Mol file: 872-05-9.mol

Synonyms:1-DECENE;Dec-1-ene;872-05-9;Decylene;n-1-Decene;1-n-Decene;alpha-Decene;n-Decylene;Gulftene 10;68037-01-4;Dialene 10;decene-1;NSC 62122;CCRIS 5718;HSDB 1073;.alpha.-Decene;EINECS 212-819-2;Decene, n-;UNII-7O4U4C718P;DTXSID8027329;CHEBI:87315;7O4U4C718P;MFCD00009577;NSC-62122;DECENE, 1-;UNII-U333RI6EB7;DTXCID507329;EC 212-819-2;25189-70-2;37309-58-3;EC 500-183-1;(C10-H20)x-;Linealene 10;Neodene 10;AHec-1-ene;DECENE [INCI];1-Decene, 94%;1-DECENE [HSDB];UNII-4U179ML4TJ;UNII-CQ4IKK1766;Alkenes, C10-16 alpha-;1-Decene, analytical standard;UNII-75Y1X69O7I;4U179ML4TJ;CQ4IKK1766;U333RI6EB7;CHEMBL3187990;1-DECENE MFC10 H20;75Y1X69O7I;UNII-4YI0729529;NSC62122;EINECS 272-492-7;Tox21_200195;LMFA11000311;1-Decene, >=97.0% (GC);AKOS015902910;1-Decene, purum, >=95.0% (GC);NCGC00248557-01;NCGC00257749-01;1-C10H20;CAS-872-05-9;LS-59413;1-DECENE [STANDARD MATERIAL FOR GC];4YI0729529;D0028;FT-0607692;S0340;EN300-384588;T73018;500-183-1 (NLP #);Q151410;W-107244;F8881-0779

Chemical Property of 1-Decene

Chemical Property:

• Appearance/Colour: clear, colorless liquid
• Vapor Pressure: 1.6 mm Hg ( 23.8 °C)
• Melting Point: -66.3 ºC
• Refractive Index: n20/D 1.421(lit.)
• Boiling Point: 169-171 ºC
• Flash Point: 49 ºC
• PSA: 0.00000
• Density: 0.741
• LogP: 3.92300
• Storage Temp.: Flammables area
• Water Solubility.: insoluble
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 140.156500638
• Heavy Atom Count: 10
• Complexity: 64.4
• Transport DOT Label: Flammable Liquid

Purity/Quality:

98% ^*data from raw suppliers

1-Decene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,F,Xn,N
• Statements: 10-38-53-65-66-50/53
• Safety Statements: 36/37-51-62-37-16-61-60

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCCCCCC=C
• Inhalation Risk: No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.
• Effects of Short Term Exposure: The substance is mildly irritating to the eyes. If swallowed the substance easily enters the airways and could result in aspiration pneumonitis.
• Effects of Long Term Exposure: The substance defats the skin, which may cause dryness or cracking.
• Uses: 1-Decene is the only isomer of industrial importance. it is used as a monomer in copolymers and is an intermediate in the production of epoxides, amines, oxo alcohols, synthetic lubricants, synthetic fatty acids, and alkylated aromatics. 1-Decene has been isolated from the leaves and rhizome of the plant Farfugium japonicum and has been detected as the initial product in the microbial degradation of n-decane.

Technology Process of 1-Decene

There total 329 articles about 1-Decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

decylbenzylpiperidinium chloride (82760-96-1) → 1-Decene (872-05-9,17438-89-0,25189-70-2) + benzyl chloride (100-44-7) + toluene (108-88-3,15644-74-3,16713-13-6)

Guidance literature:

at 250 ℃; for 0.25h; under 5E-06 Torr; Product distribution; other temperature, time and pressure; temperature influence on stability; the rates of destruction; influence of air;;

Reference yield:

Methyl oleate (112-62-9) + acrylonitrile (107-13-1,25014-41-9) → trans-9-octadecene (7206-25-9) + octadeca-9Z-ene (1779-13-1) + (Z)-undec-2-enenitrile (85520-63-4,22629-48-7) + (E)-undec-2-enenitrile (110556-25-7,22629-48-7) + dimethyl (Z)-octadec-9-ene-1,18-dioate (13481-97-5,24753-49-9,40393-46-2) + Dimethyl (E)-octadec-9-enedioate (24753-49-9) + 1-Decene (872-05-9,17438-89-0,25189-70-2) + methyl 9-decenoate (25601-41-6) + methyl (Z)-10-cyano-9-decenoate (173602-45-4) + methyl (E)-10-cyano-9-decenoate (173602-43-2)

Guidance literature:

With 1,3-bis-(2,4,6-trimethylphenyl)-2-(imidazolidinylidene)dichloro(5-nitro-2-isopropoxyphenylmethylene)ruthenium; In toluene; for 3.5h; Inert atmosphere;

Reference yield:

Methyl oleate (112-62-9) + allyl-trimethyl-silane (762-72-1) → trans-9-octadecene (7206-25-9) + Dimethyl (E)-octadec-9-enedioate (24753-49-9) + 1-Decene (872-05-9,17438-89-0,25189-70-2) + methyl 9-decenoate (25601-41-6) + methyl 11-(trimethylsilyl)undec-9-enoate + trimethyl(undec-2-en-1-yl)silane

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 50 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c6ra24200f

upstream raw materials:

diethyl ether

allyl tert-butyl ether

n-heptylmagnesium bromide

allyl n-butyl ether

Downstream raw materials:

decyl-phosphonic acid dibutyl ester

1,2-decanediol

2,2-Dimethyl dodecanoic acid

2-phenyl-dodecanoic acid

Refernces

• 1、 Geng, Jiao,Hu, Xingbang,Liu, Qiang,Wu, Youting,Yang, Liu,Yao, Chenfei. "Controlling the Lewis Acidity and Polymerizing Effectively Prevent Frustrated Lewis Pairs from Deactivation in the Hydrogenation of Terminal Alkynes". . p. 3685 - 3690. Retrieved 2021/05/31.
• 2、 Pye, Scott J.,Chalker, Justin M.,Raston, Colin L.. "Vortex Fluidic Ethenolysis, Integrating a Rapid Quench of Ruthenium Olefin Metathesis Catalysts". . p. 1138 - 1143. Retrieved 2020/08/27.