AlCl₂F₂^(1-)

Base Information

• Chemical Name: AlCl₂F₂^(1-)
• CAS No.: 109144-15-2
• Molecular Formula: AlCl₂F₂
• Molecular Weight: 135.884
• Mol file: 109144-15-2.mol

Synonyms:AlCl₂F₂^(1-)

Chemical Property of AlCl₂F₂^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of AlCl₂F₂^(1-)

There total 3 articles about AlCl₂F₂^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aluminium trichloride (7446-70-0) + {Ph3PhCH2P}{H2F3} → aluminum(III) fluoride (7784-18-1) + AlClF3(1-) (108528-94-5) + AlCl2F2(1-) (109144-15-2) + AlCl3F(1-) (109144-16-3) + tetrachloroaluminate(1-)

Guidance literature:

In dichloromethane; H2F3(1-)/AlCl3 ratio of 3:1; 25°C.; final ppt.: AlF3; 27Al-NMR;

Reference yield:

sodium tetrachloroaluminate (7784-16-9) → tetrafluoroaluminate(1-) (21340-02-3) + AlClF3(1-) (108528-94-5) + AlCl2F2(1-) (109144-15-2) + AlCl3F(1-) (109144-16-3)

Guidance literature:

With NaF; In further solvent(s); byproducts: NaCl; dissolved in molten NaF at 820 ° C (ratio F:Al = 3.0); product ratio detd. by Raman spectroscopy;

Reference yield:

sodium tetrachloroaluminate (7784-16-9) → tetrafluoroaluminate(1-) (21340-02-3) + AlClF3(1-) (108528-94-5) + AlCl2F2(1-) (109144-15-2) + AlCl3F(1-) (109144-16-3) + tetrachloroaluminate(1-)

Guidance literature:

With LiCl; NaF; In further solvent(s); byproducts: NaCl; various amounts dissolved in 80 mol-% LiCl and 20 mol-% NaF (temp. >490 ° C);

upstream raw materials:

aluminium trichloride

sodium tetrachloroaluminate

Refernces

• 1、 Gilbert,Williams, Stephen D.,Mamantov. "Raman spectroscopy of fluoride-containing chloroaluminate melts". . p. 2359 - 2363. Retrieved 2008/10/08.