methyl 5(S),6(S)-oxido-11-oxo-7-cis-9-trans-undecadienoate

Base Information Edit

Chemical Name:methyl 5(S),6(S)-oxido-11-oxo-7-cis-9-trans-undecadienoate
CAS No.:82442-92-0
Molecular Formula:C₁₂H₁₆O₄
Molecular Weight:224.257
Hs Code.:
Mol file:82442-92-0.mol

Synonyms:methyl 5(S),6(S)-oxido-11-oxo-7-cis-9-trans-undecadienoate

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Chemical Property of methyl 5(S),6(S)-oxido-11-oxo-7-cis-9-trans-undecadienoate Edit

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Technology Process of methyl 5(S),6(S)-oxido-11-oxo-7-cis-9-trans-undecadienoate

There total 41 articles about methyl 5(S),6(S)-oxido-11-oxo-7-cis-9-trans-undecadienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 55797-81-4,105453-39-2
C₂₆H₂₂O₈

: 73958-00-6,76738-48-2,77341-38-9,79356-64-2,79356-67-5,82442-92-0,92009-26-2
4-[(2S,3S)-3-((1Z,3E)-5-Oxo-penta-1,3-dienyl)-oxiranyl]-butyric acid methyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: 96 percent / benzoic acid / 1,2-dimethoxy-ethane / 4 h / Heating

2: 100 percent / H₂SO₄ / 3 h / 23 °C

3: 93 percent / 95percent zinc amalgam, dry hydrogen chloride / diethyl ether / 6 h / 15 °C

4: 100 percent / H₂ / 10percent Pd/C / methanol / 23 °C

5: 99 percent / dry hydroden chloride / 72 h / 23 °C

6: 98 percent / pyridine / 1.) 23 deg C, 6 h, 2.) 50 deg C, 3h

7: 98 percent / K₂CO₃ / methanol / 2 h / 23 °C

8: 96 percent / Collins reagent / CH₂Cl₂ / 0.25 h / 23 °C

9: 2.) aq. NaHCO₃ / tetrahydrofuran / 1 h / -78 °C

10: NEt₃ / CH₂Cl₂ / 0.25 h / -45 °C

11: phosphate buffer / -45 - 0 °C

With pyridine; hydrogenchloride; amalgamated zinc; phosphate buffer; Collins oxidation agent; sulfuric acid; hydrogen; sodium hydrogencarbonate; potassium carbonate; triethylamine; benzoic acid; palladium on activated charcoal; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; diethyl ether; dichloromethane;
DOI:10.1021/ja00524a045

Reference yield:

: 73957-95-6,74006-65-8
C₃₂H₃₀O₁₀

: 73958-00-6,76738-48-2,77341-38-9,79356-64-2,79356-67-5,82442-92-0,92009-26-2
4-[(2S,3S)-3-((1Z,3E)-5-Oxo-penta-1,3-dienyl)-oxiranyl]-butyric acid methyl ester

Guidance literature:: Multi-step reaction with 9 steps

1: 93 percent / 95percent zinc amalgam, dry hydrogen chloride / diethyl ether / 6 h / 15 °C

2: 100 percent / H₂ / 10percent Pd/C / methanol / 23 °C

3: 99 percent / dry hydroden chloride / 72 h / 23 °C

4: 98 percent / pyridine / 1.) 23 deg C, 6 h, 2.) 50 deg C, 3h

5: 98 percent / K₂CO₃ / methanol / 2 h / 23 °C

6: 96 percent / Collins reagent / CH₂Cl₂ / 0.25 h / 23 °C

7: 2.) aq. NaHCO₃ / tetrahydrofuran / 1 h / -78 °C

8: NEt₃ / CH₂Cl₂ / 0.25 h / -45 °C

9: phosphate buffer / -45 - 0 °C

With pyridine; hydrogenchloride; amalgamated zinc; phosphate buffer; Collins oxidation agent; hydrogen; sodium hydrogencarbonate; potassium carbonate; triethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1021/ja00524a045

Reference yield:

: 63753-78-6,63753-83-3
C₃₀H₂₈O₉

: 73958-00-6,76738-48-2,77341-38-9,79356-64-2,79356-67-5,82442-92-0,92009-26-2
4-[(2S,3S)-3-((1Z,3E)-5-Oxo-penta-1,3-dienyl)-oxiranyl]-butyric acid methyl ester

Guidance literature:: Multi-step reaction with 10 steps

1: 100 percent / H₂SO₄ / 3 h / 23 °C

2: 93 percent / 95percent zinc amalgam, dry hydrogen chloride / diethyl ether / 6 h / 15 °C

3: 100 percent / H₂ / 10percent Pd/C / methanol / 23 °C

4: 99 percent / dry hydroden chloride / 72 h / 23 °C

5: 98 percent / pyridine / 1.) 23 deg C, 6 h, 2.) 50 deg C, 3h

6: 98 percent / K₂CO₃ / methanol / 2 h / 23 °C

7: 96 percent / Collins reagent / CH₂Cl₂ / 0.25 h / 23 °C

8: 2.) aq. NaHCO₃ / tetrahydrofuran / 1 h / -78 °C

9: NEt₃ / CH₂Cl₂ / 0.25 h / -45 °C

10: phosphate buffer / -45 - 0 °C

With pyridine; hydrogenchloride; amalgamated zinc; phosphate buffer; Collins oxidation agent; sulfuric acid; hydrogen; sodium hydrogencarbonate; potassium carbonate; triethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1021/ja00524a045