N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate

Base Information

• Chemical Name: N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate
• CAS No.: 73377-34-1
• Molecular Formula: CF₃O₃S*C₃₉H₄₆N
• Molecular Weight: 677.871
• Mol file: 73377-34-1.mol

Synonyms:N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate

Chemical Property of N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate

There total 1 articles about N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

n-Dodecylamine (124-22-1) + 5,6,8,9-tetrahydro-7-phenyldibenzoxanthyilium triflouromethanesulphonate (73377-38-5) → N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate (73377-34-1)

Guidance literature:

In diethyl ether; at 20 ℃; for 6h;

DOI:10.1021/jo00139a024

Reference yield: 60.0%

N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate (73377-34-1) → dodecane (112-40-3)

Guidance literature:

With DBN; at 110 - 140 ℃;

Reference yield:

N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate (73377-34-1) → 5,6,8,9-tetrahydro-7-phenyldibenzolacridine (57366-68-4) + 1-dodecene (112-41-4,25067-08-7,62132-67-6) + (Z)-dodec-2-ene (7206-26-0) + (E)-2-dodecene (7206-13-5)

Guidance literature:

With triphenylpyridine; at 150 ℃; Yield given. Yields of byproduct given;

DOI:10.1039/c39810000096

upstream raw materials:

n-Dodecylamine

5,6,8,9-tetrahydro-7-phenyldibenzoxanthyilium triflouromethanesulphonate

Downstream raw materials:

5,6,8,9-tetrahydro-7-phenyldibenzolacridine

1-dodecene

(Z)-dodec-2-ene

(E)-2-dodecene

Refernces

• 1、 Katritzky, Alan R.,El-Mowafy, Azzahra M.. "The Conversion of Primary Amines into Olefins: a Mild Alternative to the Hofmann Elimination". . p. 96. Retrieved 2007/10/02.