adamantylmagnesium bromide

Base Information

• Chemical Name: adamantylmagnesium bromide
• CAS No.: 57680-77-0
• Molecular Formula: C₁₀H₁₅BrMg
• Molecular Weight: 239.438
• Mol file: 57680-77-0.mol

Synonyms:adamantylmagnesium bromide

Chemical Property of adamantylmagnesium bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of adamantylmagnesium bromide

There total 3 articles about adamantylmagnesium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

1-Adamantyl bromide (768-90-1) → 1,1'-Biadamantane (3732-31-8) + adamantane (281-23-2) + 1-adamanthanol (768-95-6) + adamantylmagnesium bromide (57680-77-0)

Guidance literature:

With magnesium; ethylene dibromide; In diethyl ether; Further byproducts given; under N₂ or Ar;

Reference yield: 58.0%

1-Adamantyl bromide (768-90-1) + diethyl ether (60-29-7,927820-24-4) → 1,1'-Biadamantane (3732-31-8) + adamantane (281-23-2) + 1-(1-Ethoxy-ethyl)-adamantane + adamantylmagnesium bromide (57680-77-0)

Guidance literature:

With magnesium; ethylene dibromide; at 35 ℃; Product distribution; Mechanism; var. concn. of 1,2-dibromoethane, other solvents; effect of stirring, reagents ratio, impurities;

DOI:10.1021/jo00142a023

Reference yield: 26.0%

1-Adamantyl bromide (768-90-1) → 1,1'-Biadamantane (3732-31-8) + adamantane (281-23-2) + adamantylmagnesium bromide (57680-77-0)

Guidance literature:

With magnesium; ethylene dibromide; In diethyl ether; at 35 ℃; for 10h; Further byproducts given. Title compound not separated from byproducts; no mechanical stirring;

DOI:10.1021/jo00142a023

upstream raw materials:

1-Adamantyl bromide

diethyl ether

Downstream raw materials:

4-Adamantan-1-yl-2,4,6-tri-tert-butyl-cyclohexa-2,5-dienone oxime

1,1'-Biadamantane

adamantane

1-adamanthanol

Refernces

• 1、 Molle, G.,Bauer, P.,Dubois, J. E.. "Formation of Cage-Structure Organomagnesium Compounds. Influence of the Degree of Adsorption of the Transient Species at the Metal Surface". . p. 4120 - 4128. Retrieved 2007/10/02.