1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene

Base Information

• Chemical Name: 1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene
• CAS No.: 70063-66-0
• Molecular Formula: C₁₆H₁₄O₅
• Molecular Weight: 286.284
• Mol file: 70063-66-0.mol

Synonyms:1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene

Chemical Property of 1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene

There total 2 articles about 1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-acetoxybuta-1,3-diene (1515-76-0,35694-19-0,35694-20-3) + 5-hydroxynaphtho-1,4-quinone (481-39-0) → 1-acetoxy-8-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene (70063-65-9) + 1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene (70063-66-0)

Guidance literature:

In water; at 25 ℃; for 44h; Yield given. Title compound not separated from byproducts;

DOI:10.1016/0040-4039(88)85158-X

Reference yield:

1-acetoxybuta-1,3-diene (1515-76-0,35694-19-0,35694-20-3) + 5-hydroxynaphtho-1,4-quinone (481-39-0) → 1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene (70063-66-0) + 1-acetoxy-8-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene (73794-49-7)

Guidance literature:

Reference yield:

1-acetoxy-5-hydroxy-9,10-dioxo-1,4,4a,9,9a,10-hexahydroanthracene (70063-66-0) → 1-hydroxyanthraquinone (129-43-1)

Guidance literature:

upstream raw materials:

1-acetoxybuta-1,3-diene

5-hydroxynaphtho-1,4-quinone

Downstream raw materials:

1-hydroxyanthraquinone

Refernces

• 1、 B?se, Dietrich,Frey, Wolfgang,Pietruszka, J?rg. "The 'Mikami'-Catalyst in Enantioselective Diels-Alder Reactions of Juglone-Based Dienophiles with Different 1-Oxygenated Dienes: An Investigation on the Substitution Pattern Dependent Regioselectivity". . p. 2524 - 2532. Retrieved 2015/12/26.