Silanamine, N-(2-phenylethyl)-1,1,1-trimethyl-

Base Information

• Chemical Name: Silanamine, N-(2-phenylethyl)-1,1,1-trimethyl-
• CAS No.: 10433-33-7
• Molecular Formula: C11H19 N Si
• Molecular Weight: 193.364
• DSSTox Substance ID: DTXSID20146393
• Nikkaji Number: J520.245K
• Wikidata: Q83011198
• Mol file: 10433-33-7.mol

Synonyms:BRN 2716449;N-(2-Phenylethyl)-1,1,1-trimethylsilanamine;SILANAMINE, N-(2-PHENYLETHYL)-1,1,1-TRIMETHYL-;Phenethylamine, TMS derivative;Silylamine, 1,1,1-trimethyl-N-phenethyl-;10433-33-7;Silanamine, 1,1,1-trimethyl-N-(2-phenylethyl)-;C11H19NSi;4-12-00-02488 (Beilstein Handbook Reference);trimethylsilylphenethylamine;(Trimethylsilyl)phenethylamine;SCHEMBL6560133;DTXSID20146393;IJDNGNISLLHUCN-UHFFFAOYSA-N;MFCD01684186;LS-145134;N-(Trimethylsilyl)-N-(2-phenylethyl)amine;N-(2-Phenylethyl)-N-(trimethylsilyl)amine #

Chemical Property of Silanamine, N-(2-phenylethyl)-1,1,1-trimethyl-

Chemical Property:

• Vapor Pressure: 0.0737mmHg at 25°C
• Boiling Point: 228.4°C at 760 mmHg
• Flash Point: 91.9°C
• Density: 0.893g/cm³
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 193.128676145
• Heavy Atom Count: 13
• Complexity: 134

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)NCCC1=CC=CC=C1

Technology Process of Silanamine, N-(2-phenylethyl)-1,1,1-trimethyl-

There total 3 articles about Silanamine, N-(2-phenylethyl)-1,1,1-trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.5%

phenethylamine (64-04-0) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → N-trimethylsilylphenethylamine (10433-33-7)

Guidance literature:

With sulfuric acid; for 2h; Heating;

DOI:10.1134/S1070363206030182

Reference yield:

chloro-trimethyl-silane (75-77-4) + 2-phenylethylamine hydrochloride (156-28-5) → N-trimethylsilylphenethylamine (10433-33-7)

Guidance literature:

With 1,1,1,3,3,3-hexamethyl-disilazane;

Reference yield:

→ N-trimethylsilylphenethylamine (10433-33-7)

Guidance literature:

Trimethylsilyldiethylamin, β-Phenylethylamin Ia;

DOI:10.1007/BF00922333

upstream raw materials:

phenethylamine

1,1,1,3,3,3-hexamethyl-disilazane

chloro-trimethyl-silane

2-phenylethylamine hydrochloride

Downstream raw materials:

phenethyl isocyanate

N-Methyl-N-phenethylamine

Refernces

• 1、 Ram, Siya,Spicer, Leonard D.. "REGIO- AND CHEMOSELECTIVE N-C BOND FORMATION VIA CARBON DIOXIDE: A NEW SOURCE OF THE METHYL GROUP, APPLICATIONS TO N-METHYLATED SECONDARY AND TERTIARY AMINES". . p. 3561 - 3572. Retrieved 2007/10/02.