phosphorus(V) fluoride tetrachloride

Base Information

• Chemical Name: phosphorus(V) fluoride tetrachloride
• CAS No.: 13498-11-8
• Molecular Formula: Cl₄FP
• Molecular Weight: 191.784
• Mol file: 13498-11-8.mol

Synonyms:phosphorus(V) fluoride tetrachloride

Chemical Property of phosphorus(V) fluoride tetrachloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of phosphorus(V) fluoride tetrachloride

There total 4 articles about phosphorus(V) fluoride tetrachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{PCl4}(1+)*{PFCl5}(1-)={PCl4}{PFCl5} (129035-45-6) → phosphorus(V) fluoride tetrachloride (13498-11-8) + phosphorus pentachloride (10026-13-8,874483-75-7)

Guidance literature:

In neat (no solvent); dissociation above 110 °C;;

Reference yield:

{PCl4}(1+)*{PF6}(1-)={PCl4}{PF6} (16919-35-0) → dichloro-trifluoro-phosphorane (13454-99-4) + phosphorus(V) fluoride tetrachloride (13498-11-8) + phosphorus pentafluoride (7647-19-0,874483-74-6)

Guidance literature:

With AsCl₃; In not given; decompn. of (PCl4)(PF6) in AsCl3 suspension;;

Reference yield:

{PCl4}(1+)*{PF6}(1-)={PCl4}{PF6} (16919-35-0) → dichloro-trifluoro-phosphorane (13454-99-4) + phosphorus(V) fluoride tetrachloride (13498-11-8) + {PCl4}(1+)*{PFCl5}(1-)={PCl4}{PFCl5} (129035-45-6) + phosphorus pentafluoride (7647-19-0,874483-74-6)

Guidance literature:

In tetrachloromethane; heating 37.3 g (PCl4)(PF6) in 38 ml boiling CCl4; evolution of PF5 and PF3Cl2 and pptn.;; isolation of the ppt., drying in vac.; removal of formed PFCl4 and CCl4 on heating on air at 80-85 °C; composition PF0.5Cl4.5;;

upstream raw materials:

{PCl₄}⁽¹⁺⁾*{PF₆}^(1-)={PCl₄}{PF₆}

{PCl₄}⁽¹⁺⁾*{PFCl₅}^(1-)={PCl₄}{PFCl₅}

Downstream raw materials:

phosphorus pentafluoride

phosphorus pentachloride

{PCl₄}⁽¹⁺⁾*{PF₆}^(1-)={PCl₄}{PF₆}

phosphorus fluoride dichloride