phosphorus dichloride trifluoride

Base Information

• Chemical Name: phosphorus dichloride trifluoride
• CAS No.: 13454-99-4
• Molecular Formula: Cl₂F₃P
• Molecular Weight: 158.875
• Mol file: 13454-99-4.mol

Synonyms:phosphorus dichloride trifluoride

Chemical Property of phosphorus dichloride trifluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phosphorus dichloride trifluoride

There total 8 articles about phosphorus dichloride trifluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorine (7782-50-5) + trifluorophosphane (7783-55-3) → {PCl4}(1+)*{PF6}(1-)={PCl4}{PF6} (16919-35-0) + dichloro-trifluoro-phosphorane (13454-99-4) + phosphorus pentachloride (10026-13-8,874483-75-7) + phosphorus pentafluoride (7647-19-0,874483-74-6)

Guidance literature:

In not given; fast react. of PF3 with Cl2 forming PF3Cl2; slow react. of PF3Cl2 forming (PCl4)(PF6) and slow react. forming PCl5 and PF5;; solid (PCl4)(PF6) contains small amounts of PCl5 or PFCl4;;

DOI:10.1016/0022-1902(60)80086-3

Reference yield:

{PCl4}(1+)*{PF6}(1-)={PCl4}{PF6} (16919-35-0) → dichloro-trifluoro-phosphorane (13454-99-4) + phosphorus(V) fluoride tetrachloride (13498-11-8) + phosphorus pentafluoride (7647-19-0,874483-74-6)

Guidance literature:

With AsCl₃; In not given; decompn. of (PCl4)(PF6) in AsCl3 suspension;;

Reference yield:

{PCl4}(1+)*{PF6}(1-)={PCl4}{PF6} (16919-35-0) → dichloro-trifluoro-phosphorane (13454-99-4) + phosphorus pentafluoride (7647-19-0,874483-74-6)

Guidance literature:

In further solvent(s); heating (PCl4)(PF6) in AsCl3 with a reflux condenser;;

upstream raw materials:

chlorine

trifluorophosphane

{PCl₄}⁽¹⁺⁾*{PF₆}^(1-)={PCl₄}{PF₆}

Downstream raw materials:

trifluorophosphane

phosphorus trichloride

hydrogenchloride

trichlorophosphate