rac-anti-naphthalene 1,2:3,4-dioxide

Base Information

• Chemical Name: rac-anti-naphthalene 1,2:3,4-dioxide
• CAS No.: 58717-74-1
• Molecular Formula: C₁₀H₈O₂
• Molecular Weight: 160.172
• Mol file: 58717-74-1.mol

Synonyms:rac-anti-naphthalene 1,2:3,4-dioxide

Chemical Property of rac-anti-naphthalene 1,2:3,4-dioxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of rac-anti-naphthalene 1,2:3,4-dioxide

There total 3 articles about rac-anti-naphthalene 1,2:3,4-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

naphthalene (91-20-3,71998-51-1,72931-45-4) → Naphthalin-dioxid (58692-14-1,58717-74-1,80582-77-0,80582-78-1,80582-79-2)

Guidance literature:

With oxygen; isobutyraldehyde; cobalt(II) porphyrin; In acetonitrile; for 3h; Ambient temperature;

DOI:10.1016/0040-4039(96)00678-8

Reference yield:

naphthalene (91-20-3,71998-51-1,72931-45-4) → syn-1,2:3,4-naphthalene dioxide (58692-14-1) + α-naphthol (90-15-3) + rac-anti-naphthalene 1,2:3,4-dioxide (58717-74-1) + [1,4]naphthoquinone (130-15-4)

Guidance literature:

With ammonium acetate; dihydrogen peroxide; Mn(TPFPP)Cl; In acetonitrile; at 20 ℃; for 6h; Further Variations:; Catalysts; Product distribution;

DOI:10.1039/b313683c

Reference yield:

→ Naphthalin-dioxid (58692-14-1,58717-74-1,80582-77-0,80582-78-1,80582-79-2)

Guidance literature:

aus Hypochlorit u. Naphthalin;

DOI:10.1021/ja00466a093

upstream raw materials:

naphthalene

Downstream raw materials:

Methanesulfonic acid (1S,2R,3R,4S)-3-methanesulfonyloxy-1,4-diphenoxy-1,2,3,4-tetrahydro-naphthalen-2-yl ester

r,t-1,4-diphenoxy-t,c-2,3-O-isopropylidene-1,2,3,4-tetrahydronaphthalene

r,t-1,4-dimethoxy-t,c-2,3-bis(tosyloxy)-1,2,3,4-tetrahydronaphthalene

Methanesulfonic acid (1R,2S,3S,4R)-3-methanesulfonyloxy-4-methoxy-1-phenoxy-1,2,3,4-tetrahydro-naphthalen-2-yl ester

Refernces

• 1、 Mandal,Khanna,Iqbal. "Cobalt(II) porphyrin: A versatile catalyst for the oxidation of organic substrates with dioxygen and 2-methyl propanal". . p. 3769 - 3772. Retrieved 2007/10/03.