Bis(trifluoromethyl)trisulfane

Base Information

• Chemical Name: Bis(trifluoromethyl)trisulfane
• CAS No.: 372-06-5
• Molecular Formula: C2F6 S3
• Molecular Weight: 234.21
• Hs Code.: 2930909090
• DSSTox Substance ID: DTXSID20190679
• Nikkaji Number: J104.382J
• Wikidata: Q83063061
• Mol file: 372-06-5.mol

Synonyms:Bis(trifluoromethyl)trisulfane;372-06-5;Trisulfide, bis(trifluoromethyl);Bis-trifluormethyl-trisulfid;bis-(Trifluoromethyl)trisulfide;SCHEMBL9298675;DTXSID20190679;Di(methyl) trisulfide, perfluoro-;1,3-Bis(trifluoromethyl)trisulfane #

Chemical Property of Bis(trifluoromethyl)trisulfane

Chemical Property:

• Vapor Pressure: 422mmHg at 25°C
• Boiling Point: 41.3°Cat760mmHg
• Flash Point: °C
• PSA: 75.90000
• Density: 1.719g/cm³
• LogP: 4.05560
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 2
• Exact Mass: 233.90663249
• Heavy Atom Count: 11
• Complexity: 100

Purity/Quality:

98%Min ^*data from raw suppliers

BIS(TRIFLUOROMETHYL)TRISULFIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)SSSC(F)(F)F

Technology Process of Bis(trifluoromethyl)trisulfane

There total 25 articles about Bis(trifluoromethyl)trisulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dimethyl(bromo)arsine (676-71-1) + Copper(I) trifluoromethanethiolate (3872-23-9) → Bis(trifluoromethyl)disulfid (372-64-5) + bis(trifluoromethyl)trisulfide (372-06-5) + bis(trifluoromethyl)tetrasulfide (372-07-6) + dimethyl(trifluoromethylthio)arsine (1959-80-4)

Guidance literature:

at 80 - 90 ℃; for 6h; Further byproducts given;

DOI:10.1016/S0022-1139(00)80466-2

Reference yield: 25.0%

ethylarsenic dichloride (598-14-1) + Copper(I) trifluoromethanethiolate (3872-23-9) → Bis(trifluoromethyl)disulfid (372-64-5) + trifluoromethylmercaptothiocarbonyl fluoride (371-73-3) + bis(trifluoromethyl)trisulfide (372-06-5) + ethyl bis(trifluoromethylthio)arsine

Guidance literature:

at 85 - 95 ℃; for 6h; Further byproducts given;

DOI:10.1016/S0022-1139(00)80466-2

Reference yield:

uranium hexafluoride (7783-81-5) → uranium(IV) tetrafluoride (10049-14-6) + bis(trifluoromethyl)trisulfide (372-06-5) + sulfur tetrafluoride (7783-60-0)

Guidance literature:

With carbon disulfide; In gaseous matrix; 25°C; diluent: He;

DOI:10.1021/ic50010a044

upstream raw materials:

carbon disulfide

dimethyl(bromo)arsine

Copper(I) trifluoromethanethiolate

ethylarsenic dichloride

Downstream raw materials:

tetramethyl-2,2,3,3 butane

diethyl sulphide

thiocarbonyl fluoride

ethyl-trifluoromethyl disulfide

Refernces

• 1、 Munavalli, S.,Muller, A. J.,Rossman, D. I.,Rohrbaugh, D. K.,Ferguson C. P.. "Synthesis of bis(trifluoromethyl)trisulfide and bis(trifluoromethylthio)selenide". . p. 37 - 40. Retrieved 1994.
• 2、 Munavalli, S.,Rossman, D. I.,Rohrbaugh, D. K.,Ferguson, C. P.,Buettner, L.. "Synthesis and biological screening of trifluoromethylthioarsenicals". . p. 15 - 20. Retrieved 2007/10/02.