trans-Styrol-dimethyldithiocarbamat

Base Information

• Chemical Name: trans-Styrol-dimethyldithiocarbamat
• CAS No.: 23846-99-3
• Molecular Formula: C₁₁H₁₃NS₂
• Molecular Weight: 223.363
• Mol file: 23846-99-3.mol

Synonyms:trans-Styrol-dimethyldithiocarbamat

Chemical Property of trans-Styrol-dimethyldithiocarbamat

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of trans-Styrol-dimethyldithiocarbamat

There total 9 articles about trans-Styrol-dimethyldithiocarbamat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(Z)-β-bromostyrene (588-73-8,1340-14-3) + sodium dimethyldithiocarbamate (128-04-1) → trans-Styrol-dimethyldithiocarbamat (23846-99-3) + Dimethyl-dithiocarbamic acid (Z)-styryl ester (110637-74-6)

Guidance literature:

With dimethylaminoacetic acid; copper(l) iodide; In N,N-dimethyl-formamide; at 110 ℃; for 22h;

DOI:10.1016/j.tetlet.2007.03.168

Reference yield: 90.0%

Triethyl-amine; compound with dimethyl-dithiocarbamic acid + (1,2-dibromoethyl)benzene (102921-26-6,93-52-7) → trans-Styrol-dimethyldithiocarbamat (23846-99-3)

Guidance literature:

With triethylamine; In acetonitrile; at 65 ℃; for 3h; stereoselective reaction;

DOI:10.1039/d2ob00315e

Reference yield: 76.0%

(E)-phenylethenyl(phenyl)iodonium tetrafluoroborate + sodium dimethyldithiocarbamate (128-04-1) → trans-Styrol-dimethyldithiocarbamat (23846-99-3)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 0.333333h;

DOI:10.1080/00397919908086455

upstream raw materials:

Thiram

(E)-(2-phenylethenyl)magnesium bromide

(iodomethyl)triphenylphosphonium iodide

benzaldehyde

Refernces

• 1、 Mondal, Manas,Saha, Amit. "One-pot two-step dithiocarbamylation of styrenes: metal-free stereoselective synthesis of styrenyl dithiocarbamates". supporting information. p. 3491 - 3494. Retrieved 2022/05/11.
• 2、 Huang, Zhi-Zhen,Wu, Lu Ling. "A novel synthesis of vinyl dithiocarbamates via phosphonium ylides". . p. 509 - 514. Retrieved 2007/10/03.