Dimethyl-dithiocarbamic acid (Z)-styryl ester

Base Information

• Chemical Name: Dimethyl-dithiocarbamic acid (Z)-styryl ester
• CAS No.: 110637-74-6
• Molecular Formula: C₁₁H₁₃NS₂
• Molecular Weight: 223.363
• Mol file: 110637-74-6.mol

Synonyms:Dimethyl-dithiocarbamic acid (Z)-styryl ester

Chemical Property of Dimethyl-dithiocarbamic acid (Z)-styryl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Dimethyl-dithiocarbamic acid (Z)-styryl ester

There total 6 articles about Dimethyl-dithiocarbamic acid (Z)-styryl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(Z)-β-bromostyrene (588-73-8,1340-14-3) + sodium dimethyldithiocarbamate (128-04-1) → trans-Styrol-dimethyldithiocarbamat (23846-99-3) + Dimethyl-dithiocarbamic acid (Z)-styryl ester (110637-74-6)

Guidance literature:

With dimethylaminoacetic acid; copper(l) iodide; In N,N-dimethyl-formamide; at 110 ℃; for 22h;

DOI:10.1016/j.tetlet.2007.03.168

Reference yield: 75.0%

[(E)-2-bromoethenyl]benzene (588-72-7,1340-14-3) + sodium dimethyldithiocarbamate (128-04-1) → trans-Styrol-dimethyldithiocarbamat (23846-99-3) + Dimethyl-dithiocarbamic acid (Z)-styryl ester (110637-74-6)

Guidance literature:

With dimethylaminoacetic acid; copper(l) iodide; In N,N-dimethyl-formamide; at 110 ℃; for 22h;

DOI:10.1016/j.tetlet.2007.03.168

Reference yield:

(iodomethyl)triphenylphosphonium iodide (3020-28-8) + benzaldehyde (100-52-7) + sodium dimethyldithiocarbamate (128-04-1) → N,N,S-trimethyldithiocarbamate (3735-92-0) + trans-Styrol-dimethyldithiocarbamat (23846-99-3) + Dimethyl-dithiocarbamic acid (Z)-styryl ester (110637-74-6)

Guidance literature:

In N,N-dimethyl-formamide; at 85 ℃; for 2h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/jo00233a008

upstream raw materials:

(iodomethyl)triphenylphosphonium iodide

benzaldehyde

sodium dimethyldithiocarbamate

Dimethylthiocarbamoylsulfanylmethyl-triphenyl-phosphonium; iodide

Refernces

• 1、 Liu, Yunyun,Bao, Weiliang. "A new method for the synthesis of dithiocarbamates by CuI-catalyzed coupling reaction". . p. 4785 - 4788. Retrieved 2008/02/07.