Diethyl hexafluoroglutarate

Base Information

• Chemical Name: Diethyl hexafluoroglutarate
• CAS No.: 424-40-8
• Molecular Formula: C9H10F6O4
• Molecular Weight: 296.166
• Hs Code.: 2917190090
• European Community (EC) Number: 207-035-2
• NSC Number: 63360
• DSSTox Substance ID: DTXSID3059977
• Nikkaji Number: J122.444A
• Wikidata: Q81985275
• Mol file: 424-40-8.mol

Synonyms:Diethyl hexafluoroglutarate;424-40-8;Diethyl perfluoroglutarate;Diethyl 2,2,3,3,4,4-hexafluoropentanedioate;Diethyl hexafluoropentanedioate;Hexafluoroglutaric acid diethyl ester;Pentanedioic acid, hexafluoro-, diethyl ester;NSC 63360;GLUTARIC ACID, HEXAFLUORO-, DIETHYL ESTER;Hexafluoropentanedioic acid diethyl ester;DIETHYLHEXAFLUOROGLUTARATE;EINECS 207-035-2;Diethylester kyseliny hexafluorglutarove;BRN 1804802;Diethylester kyseliny hexafluorglutarove [Czech];3-02-00-01693 (Beilstein Handbook Reference);Pentanedioic acid, 2,2,3,3,4,4-hexafluoro-, 1,5-diethyl ester;C9H10F6O4;diethyl-hexafluoroglutarate;SCHEMBL4007477;DTXSID3059977;MSDPXVBLFJODJO-UHFFFAOYSA-;Hexafluroglutaric acid diethyl ester;NSC63360;MFCD00015156;NSC-63360;AKOS015852724;LS-71995;CS-0320089;FT-0626996;H0744;D90940;diethyl 2,2,3,3,4,4,-hexafluoropentanedioate;2,2,3,3,4,4-Hexafluoropentanedioic Acid Diethyl Ester;6-AMINO-6,7,8,9-TETRAHYDRO-5H-BENZOCYCLOHEPTEN-5-OLHYDROCHLORIDE

Chemical Property of Diethyl hexafluoroglutarate

Chemical Property:

• Vapor Pressure: 0.0935mmHg at 25°C
• Refractive Index: 1.3599
• Boiling Point: 224 °C at 760 mmHg
• Flash Point: 86.9 °C
• PSA: 52.60000
• Density: 1.365 g/cm³
• LogP: 2.01850
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 8
• Exact Mass: 296.04832777
• Heavy Atom Count: 19
• Complexity: 323

Purity/Quality:

98%,99%, ^*data from raw suppliers

Diethyl 2,2,3,3,4,4-Hexafluoropentanedioate >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)C(C(C(C(=O)OCC)(F)F)(F)F)(F)F
• Uses: Diethyl Hexafluoroglutarate can be used for oil production process for selective water plugging method of oil wells.

Technology Process of Diethyl hexafluoroglutarate

There total 11 articles about Diethyl hexafluoroglutarate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

ethanol (64-17-5) + hexafluoroglutaric acid (376-73-8) → diethyl perfluoroglutarate (424-40-8)

Guidance literature:

With hydrogen cation; Heating;

DOI:10.1016/S0040-4039(98)02688-4

Reference yield: 64.0%

nonafluoro-2,3,4,5-tetrahydropyridine (714-37-4) + ethanol (64-17-5) → diethyl perfluoroglutarate (424-40-8)

Guidance literature:

In ethanol; 100 °C, 28 d;;

Reference yield: 46.0%

ethanol (64-17-5) + perfluoro-N-fluoropiperidine (836-77-1) → diethyl perfluoroglutarate (424-40-8)

Guidance literature:

In ethanol; 100 °C, 28 d;;

upstream raw materials:

ethanol

hexafluoroglutaric acid

diethyl 2,2,4,4,-tetrafluoro-3-oxopentanedioate

perfluoro-N-fluoropiperidine

Downstream raw materials:

C₁₇H₁₀F₆N₈O₈

3,3,4,4,5,5-Hexafluoro-1,7-diphenyl-heptane-1,2,6,7-tetraone

1,2-bis(5'-formyl-2'-methylthien-3'-yl)perfluorocyclopentene

2,2,3,3,4,4-hexafluoro-1,5-diphenylpentane-1,5-dione

Refernces

• 1、 -. "Method for preparing fluorine-containing dihydric alcohol from fluorine-containing cycloolefin". Paragraph 0060. . Retrieved 2021/07/01.
• 2、 Lucas, Linda N.,Van Esch, Jan,Kellogg, Richard M.,Feringa, Ben L.. "A new synthetic route to symmetrical photochromic diarylperfluorocyclopentenes". . p. 1775 - 1778. Retrieved 2007/10/03.